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Synthesis and Electrochemical Properties of N-(ferrocenylmethyl)aminobenzonitrile and N-(ferrocenylmethyl)nitroaniline Derivatives

Boubekri C., Khelef A., Terki B., Lanez T.

International Letters of Chemistry, Physics and Astronomy

2015

Vol. 49

27--34

Seven novel ferrocene derivatives containing (methylamino)benzonitrile and N-methylnitroaniline groups (3a-3f and 4) have been synthesized by conventional methods and characterized by FT-IR, NMR and cyclic voltammetry. The electrochemical behavior of these compounds (3a-3f) has been studied by cyclic voltammetry measurements at a platinum electrode in acetonitrile/0.1 M TBAP. The ferrocenyl group in all compounds showed similar reversible one-electron redox process, suggesting that the ferrocene moieties are equivalent and that there are no interactions among them. The formal potential, , is shifted to the more positive potential, indicating that the (methylamino)benzonitrile and N-methylnitroaniline introduced to ferrocene moiety exercise an electron-withdrawing effect.

The Effect of Hydrazide group on the oxydation of ferrocene at two different electrodes using Rotating Disk Electrode (RDE) in organic medium

Nacer S. N., Lanez T.

International Letters of Chemistry, Physics and Astronomy

2013

Vol. 7, iss. 1

1--7

Through this work we adopted Rotating Disk Electrode (RDE) Voltammetry to study the kinetics of oxidation and the effect of hydrazide group on ferrocene in organic medium. Thus, two different electrodes (Pt and Ge) were used in order to determine this latter. According to the ferrocene taken as a witness the hydrazide group related to the ferrocene made oxidation more difficult. This ferrocenic derivative showed an electrochemical stability, a reversible electrochemical system and an electronic attractor effect of these substitutional ferrocene groups. Finally, we calculated some electrochemical parameters which were: the diffusion coefficients (D), the layer thickness in addition to the electron transfer rate.

Electrochemical properties of N'-ferrocenylmethyl-N'-phenylbenzohydrazide in aqueous and organic mediums

Nacer S.N., Lanez T.

International Letters of Chemistry, Physics and Astronomy

2013

Vol. 5

76-85

We carried out a detailed study of the kinetics of oxidation of N'-ferrocenylmethyl-N'-phenylbenzohydrazide (FcX) to ferrocenium ion (FcX+) in aqueous and organic mediums. This study using cyclic (CV) and rotating disk electrode (RDE) voltammetry showed that the FcX/FcX+ redox couple is reversible. The N'-ferrocenylmethyl-N'-phenylbenzohydrazide and ferrocenium ion diffusion coefficients (D) were calculated from these results. In addition, the electron transfer rate constant and the exchange current density for the oxidation of ferrocene were determined. A comparison of the kinetic data obtained from the two electrochemical techniques appears to show that the data from the RDE experiments are more reliable because they are collected under strict mass transport control.

Calculation of Diffusion Coefficients for Oxidation of ferrocene derivative synthesized at two different electrodes using Rotating Disk Electrode (RDE)

Nacer S.N., Khelef A., Lanez T.

International Letters of Chemistry, Physics and Astronomy

2013

Vol. 9, iss. 1

39-47

The electrochemical behavior of N'-Ferrocenylmethyl-N'-Phenylbenzohydrazide synthesized is studied by Rotating Disk Electrode (RDE) Voltammetry to study the kinetics of oxidation and the effect of hydrazide group on ferrocene in organic medium. Thus, two different electrodes (Pt and Gc) were used in ordre to determine this latter. According to the ferrocene taken as a witness the hydrazide group related to the ferrocene made oxydation more difficult. This ferrocenic derivative showed an electrochemical stability, a reversible electrochemical system and an electronic attractor effect of these substitutional ferrocene groups. Finally, we calculated some electrochemical parameters which were: the diffusion coefficients (D), the layer thickness in addition to the electron transfer rate.