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Coloration of poly(lactic acid) based textiles – a review

Baig Gulzar Ahmad

Polimery

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2020

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T. 65, nr 6

415--429

EN

Polyester fibers include industrially important cellulose acetate, poly(ethylene terephthalate) (PET), poly(1,4-cyclohexane dimethylene terephthalate) (PCDT), poly(trimethylene terephthalate) (PTT), poly(lactic acid) (PLA) fibers; however, it is the last one that has been considered to be a “green“ one. PLA is an eco-friendly polyester material that is obtained from renewable resources. The effect of chromophoregens and substituents on exhaustion, colorimetric and fastness properties of PLA with newly developed disperse dyes has been outlined. The differences in colorimetric properties, wavelength-shift and deep-dyeing behavior of PLA as compared to PET have been explained. Use of non-aqueous dyeing media such a super critical carbon dioxide (sc-CO2 ), various organic solvents and carriers have been discussed.

PL

Ważne dla przemysłu włókna poliestrowe bazują na: octanie celulozy, poli(tereftalanie etylenu) (PET), poli(tereftalanie 1,4-cykloheksanodimetylenu) (PCDT), poli(tereftalanie trimetylenu) (PTT) i, ostatnio uznanym za „zielony”, poli(kwasie mlekowym) (PLA). PLA to ekologiczny materiał poliestrowy pozyskiwany z zasobów odnawialnych. W artykule omówiono wpływ chromoforegenów i podstawników obecnych w cząsteczkach nowo opracowanych barwników dyspersyjnych na właściwości zmęczeniowe, kolorymetryczne i trwałość barwionych włókien PLA. Wyjaśniono różnice we właściwościach kolorymetrycznych, przesunięciu długości fali i głębokości zabarwienia PLA i PET. Przedstawiono zastosowanie w procesie barwienia włókien PLA niewodnych środków barwiących, takich jak: nadkrytyczny ditlenek węgla (sc-CO2 ), różne rozpuszczalniki organiczne i nośniki.

2

New arylhydrazonothiazolidin-5-one disperse dyes for dyeing polyester fibers

Metwally M.A., Khalifa M.E., Attia E.A., Amer F.A.

Polish Journal of Chemical Technology

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2010

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Vol. 12, nr 1

1-6

EN

A series of new thiazolidin-5-one disperse dyes was synthesized from the reactions of 2-substituted 3-phenylthiazolidinones with various aryldiazonium chlorides. The synthesized dyes were characterized by UV-visible absorption, IR, NMR and MS spectroscopy. The dyes gave orange to reddish-violet shades with very good depth on polyester fibers. The dyed fabrics show moderate to good fastness to light and very good to excellent fastness to washing and perspiration. Also, the assessment of color coordinates was discussed.

3

Synthesis and application of melamine urea based precondensates

Bhatti K. P, Zuber M.

Autex Research Journal

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2009

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Vol. 9, no. 4

121--124

EN

Formaldehyde based low molecular weight precondensates (fixers) are always have very important role in processing of woven fabrics. Two important applications of these chemicals are in fixing of dyes and improvement of crease resistant behavior of fabrics. The synthesis of a series of precondensates by the reaction of formaldehyde with various percent mole ratios of melamine/urea is described which belong to the class of thermosetting resins. The dyed cotton specimens were impregnated with fixers and cured at 150°C for 3 minutes using acetic acid curing catalyst. The rubbing fastness to crocking, color fastness to washing and light fastness is reported and found to be dependent on the fixing efficiency of precondensate to dye. Precondensate based on 50:50% mole ratio of melamine-urea-formaldehyde showed the excellent fixing efficacy. The fastness to light is found to be dependent on the aromatic character of melamine ring which obviously is due to the preferably absorption in the UV region. The fabrics with an intense color and good characteristics were obtained thus presenting a possibility for extension of the applied in practice textile precondensates.