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EN
Many open-pit mines are gradually converted to underground mining, the problem of roadway surrounding rock damage caused by expansive soft rock is becoming increasingly problematic. To study the seasonal evolution of expansive rock mass containing clay minerals, an underground mine transferred from an open-pit was selected as the experimental mine. The experimental results of SEM electron microscopy and X-ray diffraction confirmed that the surrounding rock of the main haulage roadway contains a large number of expansive clay minerals. The expansive grade of the main transport roadway’s surrounding rock could then be identified as the medium expansive rock mass, which has a large amount of exchangeable cation and strong water absorption capacity, based on the combined test results of dry saturated water absorption and free expansion deformation. The water swelling can cause the roadway to considerably deform, and then the surrounding rock will have strong rheological characteristics. From the research results in the text, the seasonal evolution law of the main haulage roadway in the experimental mine was obtained, and the deformation law of the expansive rock mass under different dry and wet conditions was revealed. The research results provide a reference for studying the stability evolution law of expansive soft rocks in underground mines.
EN
Recent advances in the construction of speed of sound meters made high-accuracy routine measurements possible in laboratories non-specialized in physical acoustics. Reliable values of the isentropic compressibility can be obtained from speeds of sound and densities of liquids using the Laplace formula. Strict thermodynamic relationships connect the isentropic compressibility of a medium and its density as a function of temperature and pressure with the heat capacity. These relationships result from the principles of thermodynamics and require no approximations or molecular models. In this study, the heat capacities of twelve liquids: hydrocarbons, acetonitrile, and ionic liquids were calculated from the speeds and densities taken from the literature sources. The agreement of the calculation results with the reference heat capacities, either critical values or measured calorimetrically, was satisfactory. The relative uncertainty of the calculated heat capacities was rather conservatively estimated for 5%. If the measurement procedures were optimized for heat capacity determination, better results would be attained, with the uncertainty probably smaller than 1%. Thus, the speed-and-density method is a potential alternative to classical calorimetry.
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