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1 Polish Journal of Chemical Technology

1 2001

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Synthesis of the glycidol over aluminosilicate Ti-Beta catalyst

Wróblewska A., Milchert E.

Polish Journal of Chemical Technology

2001

Vol. 3, nr 3

29-32

The epoxidation of allyl alcohol by a 30% hydrogen peroxide over Ti-BETA catalyst has been investigated. Two types of solvents: aprotic (acetone) and protic (methanol) were used in the studies. The optimum conditions were found for the epoxidation of allyl alcohol in the presence of acetone and methanol. The effect of the temperature (20 - 120°C), the molar ratio AA/H2O2 (1 - 10:1 mol/mol), solvent concentration (10 - 80 wt %), catalyst concentration (0.1 - 2.0 wt %) and reaction time (1 - 8 h) were studied. The optimum parameters were: temperature 20°C, the molar ratio of AA/H0 = 1, catalyst concentration 0.5 wt %, reaction time lh but the solvent concentration in the reaction mixture was different and amounted to 40 wt % for acetone and 80 wt % for methanol.