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PEDOT:PSS thin film for photovoltaic application

Weszka J., Szindler M., Jarka P.

Journal of Achievements in Materials and Manufacturing Engineering

2013

Vol. 59, nr 2

59—66

Purpose: The aim of this paper was to investigate changes in surface morphology and optical parameters of thin films of poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS). Thin films were prepared using spin coating method. Design/methodology/approach: The thin films of PEDOT:PSS was investigate by Raman scattering technique in Raman spectrometer. The changes in surface topography were observed with the atomic force microscope AFM XE-100. The results of roughness have been prepared in the software XEI Park Systems. The measurement of optical parameter was performed using spectrometer UV/VIS and spectroscopic ellipsometer. Findings: Results and their analysis allow to conclude that the PEDOT:PSS solution concentration and spin speed, an important factor in spin coating technology, have a significant influence on surface morphology and optical reflection of thin films. Practical implications: Knowledge about the sol gel PEDOT:PSS optical parameters and the possibility of obtaining a uniform thin films show that it can be good material for photovoltaic and optoelectronic devices. Originality/value: The paper presents some researches of PEDOT:PSS thin films deposited by spin coating method on glass substrate.

Electroconductive polymers in (bio)chemical sensors

Pijanowska D. G., Kossakowska A., Torbicz W.

Biocybernetics and Biomedical Engineering

2011

Vol. 31, no. 4

43-57

In this paper, research concerning application of electroconducting polymers in biosensors is discussed. Selection of the electropolymers has been limited to those which monomers are water-soluble, such as: polypyrrole and polyaniline. In general, experiments concerning EP utilization in dehydrogenase based biosensors were divided in four stages: (I) incorporation of mediators as dopants of the EP's layer, (2) immobilization of cofactors e.g. NAD+/NADH, (3) immobilization of enzymes and (4) immobilization of all components: mediator, cofactor and enzyme. As a dopant of the PPy water-soluble electroactive compound ferrocyanide was used. Another EP, namely polyaniline was also tested as an electrode material for NADH detection based on its electrochemical oxidation. In the case of simultaneous immobilization of mediator, NAD, and ADH in the PPy layer, as a result of the ethanol oxidation, the oxidation peaks of the mediator become smaller whereas the oxidation peaks of PPy increase. In the analyzed EtOH concentration range (O - 2 mM), slope of calibration curve for the PPy oxidation peak was around 20 \miA/mM. In the case of PAn deposition on the platinum electrode, decrease of the oxidation potential for NADH by 0.4 V was observed.