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Study on Inhibition of N80 Carbon Steel in 0.5M KCl Solution Saturated with CO2 by Gum Arabic

Palumbo G., Banaś J.

Journal of Casting & Materials Engineering

2018

Vol. 2, no. 1

5--8

The effect of Gum Arabic (GA) on the corrosion of an N80 carbon steel pipeline in a CO2 -saturated chloride (0.5M KCl) solution was investigated through AC impedance and polarization curves. Potentiodynamic measurements showed that the corrosion current density decreased in the presence of inhibitors and that the inhibitor acts like a mixed-type inhibitor, with anodic predominance. The Nyquist diagrams showed an increase in polarization resistance values in the presence of the inhibitor, thus increasing inhibition efficiency. At higher temperatures, the inhibition efficiency decreased, implying that the inhibition action of GA occurred via the physical adsorption process. The activation parameters of the corrosion process such as activation energies, Ea, and the heat of adsorption, Qads, were calculated, respectively, by the obtained corrosion rate and inhibition efficiency at different temperatures. At higher temperatures, the increase in activation energy combined with the negative levels of the heat of adsorption further supported the physical adsorption nature of the process.

Rola elektrochemii w ochronie środowiska

Grodzka E., Winkler K., Koczorowski Z.

Wiadomości Chemiczne

2006

[Z] 60, 9-10

671-702

For decades electrochemical technology has contributed successfully to environmental protection. Electroanalytical techniques have been frequently used in monitoring the changes of environment. In industry, electrochemical technologies can provide higher purity in technological processes and they can also limit a degradation of the environment in comparison to the common chemical methods. Electrochemistry has been also very useful in developing and in the production of new energy sources. A lot of attention has been paid to studies of environmentally friendly hydrogen fuel cells. The electrochemical techniques of waste degradation can be divided into two main categories: (i) techniques based on the faradaic processes of oxidation or reduction of contamination, and (ii) electrokinetic methods based on the transport of ions or charged particles in the electric field. The electrode processes result in the formation of deposits on the electrode surface or the decomposition of large organic molecules to the low molecular weight, easily biodegradable molecules or CO2. The electrokinetic techniques include electrocoagulation, electroosmosis, electrodialysis, and electroflotation. These techniques are widely used in removing contaminants from soil. This paper is focused on selected topics related to the environmentally friendly application of electrochemistry.