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2 Journal of Achievements in Materials and Manufacturing Engineering

2 2012

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Researches of topography and optical properties of the thin films NiPc/PTCDA donor acceptor couple

Weszka J., Jarka P., Chwastek-Ogierman M., Hajduk B.

Journal of Achievements in Materials and Manufacturing Engineering

2012

Vol. 53, nr 2

81--88

Purpose: The aim of this work consists of researches of surface topography and optical properties of organic thin films of NiPc : PTCDA blends deposited by thermal evaporation from one source. Thin films of organic materials are provided as donor/acceptor couple in heterojuction solar cells. Design/methodology/approach: Films consisting of NiPc and PTCDA mixture were deposited by thermal evaporation from one source. By using blends with different PTCDA to NiPc ratios and steering the temperature of the sources and hence deposition rate different properties of layers are obtained. Findings: Both the chemical composition and technological parameters of deposition process has appeared to influence on optical properties and surface morphology of thin films. These parameters were found to influence surface morphology and UV-Vis absorption spectra. Research limitations/implications: The paper shows the methodology of deposition NiPc/PTCDA donor/ acceptor blends and the influence of evaporation parameters on properties of thin films. That can be used for the research of the planar heterojunction solar cells based on NiPc/PTCDA heterojunction donor-acceptor couple active layers. Practical implications: Results of researches suggest that blends of NiPc and PTCDA can be useful materials in organic photovoltaic device. However right deposition parameters and the blends proportions determine the properties of NiPc/PTCDA donor/acceptor thin films. Originality/value: The goal of this paper is to definie the surface topography and optical properties of thin films NiPc/PTCDA blends prepared with different proportions of components and parameters of evaporation process.

Investigations of morphology and optical properties of thin films of TiOPc/PTCDA donor acceptor couple

Weszka J., Jarka P., Hajduk B., Chwastek-Ogierman M.

Journal of Achievements in Materials and Manufacturing Engineering

2012

Vol. 55, nr 2

396--402

Purpose: The aim of this work is studying surface topography and optical properties of organic thin films of TiOPc and PTCDA blends deposited by thermal vacuum evaporation. Design/methodology/approach: Thin films of blends of organic materials are provided as donor/acceptor couples in bulk heterojunction based organic solar cells. Thin films of TiOPc - PTCDA mixture have been deposited by thermal vacuum evaporation from one source with various ratios of blends components and deposition rates used. Both the chemical composition and technological parameters of the deposition process have appeared to influence on optical properties, UV-Vis absorption spectra in particular, and surface morphology of the as-prepared thin films. The paper reveals the methodology of deposition thin films of TiPc-PTCDA donor/ acceptor blends and the influence of deposition parameters on their properties. Findings: Thin films of such blends can be used for the research on the planar heterojunction solar cells based on donor-acceptor couple active layers. Results of these investigations suggest that blends of TiOPc and PTCDA can be suitable materials for preparing organic photovoltaic devices. Research limitations/implications: Deposition parameters and proportions of the blend components used determine the properties of TiOPc/PTCDA thin films. Originality/value: The goal of this paper is also to define relations connecting the surface morphology and optical properties of thin films of TiOPc-PTCDA blend prepared with their composition and parameters of the evaporation process.