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Detonation Characteristics of Gaseous Isopropyl Nitrate at High Concentrations

Zeng Linghui, Liang Huimin, Zhang Qi

Central European Journal of Energetic Materials

2021

Vol. 18, no. 2

245--270

Isopropyl nitrate (IPN) is a component of propellant fuel. High concentrations of IPN can still produce detonation. To date, very limited literature is available regarding high concentrations of IPN detonations. The detonation pressure is related to the equivalence ratio and density of IPN/air mixtures. These two factors have opposing effects on the detonation of an IPN/air mixture. The detonation characteristics of gaseous IPN/air mixtures at high concentrations (300-4000 g/m3) have been studied numerically. The results showed that when the IPN concentration is 300-600 g/m3, density played a dominant role on detonation. The maximum detonation pressure, 2.81 MPa, and the maximum detonation velocity, 1890 m/s, occurred at a concentration of 600 g/m3 (equivalence ratio Φ = 2.15). When the IPN concentration was increased from 300 to 600 g/m3, the peak overpressure and velocity increased by 19.6% and 6.2%, respectively. When the IPN concentration is higher than 600 g/m3, the equivalence ratio is extremely large and the detonation properties were seriously degraded. An analysis of the detonation products illustrated the burn-off rate of high concentrations of IPN and the influence of the detonation product CH3CHO. At a concentration of 600 g/m3, the IPN/air mixture can achieve optimal detonation properties and fuel economy.

Software Development for the Detonation Product Analysis of High Energetic Materials - Part I

Muthurajan H., Ghee H.

Central European Journal of Energetic Materials

2008

Vol. 5, nr 3-4

19-35

The detonation of energetic materials will result in the formation of decomposition products. These may be carbon monoxide, carbon dioxide, carbon, water, etc. In order to clarify the problems of decomposition products, a software package is developed to solve the problems of decomposition products using four different concepts. Although each concept will provide a different answer for the decomposition products they can be used as a guide and give fairly good approximations. This paper describes the development of a software package to estimate the possible decomposition products and the results generated using the software package LION. An algorithm to compute the detonation products of energetic materials using four different concepts along with the computation of oxygen balance, elemental composition, and molecular weight has been developed and described in this paper. The concept or predicting possible detonation products is particularly useful as one of the guideline for screening the potential molecules, when formulating explosives to produce a minimum toxic fumes to reduce the toxic hazardous to the users.