Wyniki wyszukiwania - BazTech

1

Microstructure and surface free energy of light-cured dental composites after their modification with liquid rubber

Sowa Monika, Przekora Agata, Pałka Krzysztof

Engineering of Biomaterials

|

2022

|

vol. 25, no. 164

9--15

EN

The use of liquid rubber as a component of light-cured dental composites is one of the methods of increasing their fracture toughness. It also reduces polymerization shrinkage and offers the potential to lower water sorption. The aim of the study was to evaluate the miscibility of liquid rubber in composite matrix resins as well as changes in the wettability and surface free energy (SFE) values of commercial lightcuring composites after their modification with liquid rubber. The research materials were Flow Art and Boston (Arkona) light-cured composites and resin mixtures used in their production. Liquid rubber Hypro 2000X168LC VTB (Huntsman Int.) was used as a modifier. The solubility of liquid rubber was assessed under light microscopy. The contact angle and SFE measurements were made on a DSA30 goniometer (Kruss) using water and diiodomethane. It was found that the liquid rubber solubility depended mainly on the viscosity of the resin, which was related to the amount of BisGMA. The resulting mixture showed good temporal stability without larger domains. The curing process released the liquid rubber as a separate phase formed as spherical domains. The morphology of these domains was homogeneous and their size did not exceed 50 µm in diameter. The presence of liquid rubber in modified composites increased their hydrophobicity and reduced the surface free energy value. The obtained properties might help to reduce the formation of bacterial biofilm on dental fillings.

2

Charakterystyka kompozytowych materiałów stomatologicznych stosowanych w gabinetowych systemach CAD/CAM

Rogula Jakub, Kuźniar-Folwarczny Agnieszka, Sulewski Mikołaj, Błaszczyk Anna, Sulewska Agnieszka, Kosior Piotr, Dobrzyński Maciej

Inżynier i Fizyk Medyczny

|

2020

|

Vol. 9, nr 1

57--61

PL

Praca zawiera charakterystykę materiałów kompozytowych i hybrydowych stosowanych w gabinetowych systemach CAD/ CAM, jak również opis procedury zabiegowej podczas leczenia pacjenta z zastosowaniem jednego z nich. Materiały kompozytowe stosowane powszechnie do odbudowy bezpośredniej zębów posiadają wady, które zostały wyeliminowane w prefabrykowanych bloczkach zdatnych do obróbki skrawaniem. Frezowanie pracy ostatecznej podczas tej samej wizyty umożliwia uzyskanie uzupełnienia o lepszych właściwościach fizyko-chemicznych, lepszej estetyce i pozbawionego takich wad jak skurcz polimeryzacyjny, w podobnym czasie, co standardowe leczenie zachowawcze.

EN

The work contains the characteristics of composite and hybrid materials used in the office CAD/CAM systems, as well as a description of the procedure during treatment of the patient using one of them. Composite materials commonly used for direct tooth reconstruction have defects that have been eliminated in prefabricated blocks suitable for machining. Milling the final work during the same visit makes it possible to obtain a restoration with better physico-chemical properties, better aesthetics and free of defects such as polymerization shrinkage. All that is at a similar time as standard conservative treatment.

3

Polymerization shrinkage of resin mixtures used in dental composites

Pałka Krzysztof, Janiczuk Patrycja, Kleczewska Joanna

Engineering of Biomaterials

|

2020

|

Vol. 23, no. 154

16--21

EN

Polymerization of dental composites generates shrinkage in the matrix resulting in numerous clinical problems. The influence of the most commonly used resins on the shrinkage process has not been thoroughly examined so far in the literature. The purpose of this work is to determine the effect of the resin mixture compositions on the volumetric polymerization shrinkage. The mixtures used in the tests were pre-pared in specific weight proportions to determine the influence of particular monomers, such as Bis-GMA, Bis-EMA, UDMA, and TEGDMA. The shrinkage measurements were performed using the self-designed video-imaging device. The studies showed that the shrinkage decreased in opposite to the Bis-GMA concentration in the mixture with the simultaneous decrease in the Bis-EMA content. The shrinkage value decreased in opposite to the molecular weight only for some monomers and compositions. Bis-EMA resin as a flexible monomer achieved the lower shrinkage values than UDMA, and the highest shrinkage values, above 6%, were achieved by compositions with the 14wt% content of Bis-GMA. Regarding the shrinkage, the most optimal composition was 56wt% Bis-GMA with the addition of Bis-EMA (24wt%) and TEGDMA (20wt%). The obtained shrinkage value was 4.73%.

4

Wpływ modyfikacji nanocząstek krzemionki na wybrane właściwości eksperymentalnego kompozytu stomatologicznego

Szczesio A., Sokołowski J., Kałuzińska K., Lauk K., Troć L., Bociong K.

Przemysł Chemiczny

|

2018

|

T. 97, nr 4

591--594

PL

Zbadano wpływ rodzaju nanocząstek krzemionki na wybrane właściwości mechaniczne eksperymentalnego kompozytu stomatologicznego. Badania uwzględniały ocenę twardości, średnicowej wytrzymałości na rozciąganie oraz wytrzymałości na zginanie. Nanokompozyty charakteryzują się zadowalającymi właściwościami, przy założeniu, że zmodyfikowane materiały nie będą stosowane w obrębie powierzchni zwarciowych. Nie zauważono wpływu rodzaju modyfikatora powierzchni nanocząstek krzemionki na właściwości wytrzymałościowe badanych kompozytów. Najniższe wartości naprężeń skurczowych zaobserwowano dla krzemionki Aerosil R202.

EN

Three types of modified silica nanoparticles were added sep. (40% by mass) as fillers to dimethacrylate resin-matrix, then light-cured and tested for usefulness of the composites in dentistry. The tests were made also for composites without any addn. of fillers. The addn. of fillers resulted in increasing the bending strength, flexural modulus and microhardness as well as in reduction of diam. tensile strength.

5

Naprężenia skurczowe generowane podczas fotoutwardzania eksperymentalnego kompozytu stomatologicznego. Cz. 2

Bociong K., Nowak J., Szczesio A., Krasowski M., Sokołowski K., Domarecka M., Sokołowski J.

Przemysł Chemiczny

|

2017

|

T. 96, nr 7

1490--1492

PL

Badano naprężenia skurczowe generowane podczas fotoutwardzania eksperymentalnego kompozytu stomatologicznego, jak również materiału, do którego dodano 1-10% mas. dimetakrylanu diuretanu lub dimetakrylanu 1,6-heksanodiolu (monomery). Na podstawie uzyskanych wyników stwierdzono, że eksperymentalny kompozyt stomatologiczny oraz jego analog zmodyfikowany dimetakrylanem diuretanu (1 lub 5% mas.) generują niewielkie naprężenia skurczowe, znacznie mniejsze od naprężeń generowanych podczas naświetlania komercyjnych materiałów żywiczych o tradycyjnym składzie osnowy polimerowej.

EN

An expt. dental composite was modified by addn. of diurethane or 1,6-hexanediol dimethacrylate (1-10% by mass), photocured and studied for shrinkage stress during its curing. The stress was significantly smaller in comparison with com. dental composite materials.

6

Temperature changes influenced by different types of light curing units during polymerization of resin-based dental composite materials

Malara P, Świderski W., Świderska J.

Archives of Materials Science and Engineering

|

2016

|

Vol. 79, nr 2

64--70

EN

Purpose: of this study was to evaluate the influence of LCU type on temperature changes during polymerization of two resin-based composites with different matrices (silorane-based and methacrylate-based). Design/methodology/approach: The light-curing units (LCUs) selected for this study included three various LEDs (LED 55, LED 10W and Radii Plus) and a QTH (Elipar Highlight). Two different resin-based composites (RBCs) were used in this study. The silorane-based composite Filtek Silorane and methacrylate-based composite Filtek P60. Temperature changes were measured during polymerization with LCUs working in various curing modes. Empty mold, Filtek Silorane RBC and Filtek P60 RBC were cured from a distance of 0 mm, 2.5 mm and 5 mm. Findings: Regardless the type of RBC, every time the highest temperature was reached with LED 55 light-curing unit. Comparing Filtek Silorane and Filtek P60 RBCs, the temperature of Filtek Silorane RBC was significantly higher with LED 55 (35.4±4.9), Radii Plus (33.5±5.5) and Elipar Highlight LCUs (31.2±3.1), and significantly lower with LED 10W LCU (28.5±7.5). For Filtek P60 the measured temperatures of polymerization were 32.7±3.2 for LED 55 LCU, 29.9±5.6 for LED 10W LCU, 31.0±2.4 for RadiiPlus LCU and 30.2±1.8 for Elipar Highlight LCU. Research limitations/implications: The research was carried out for two groups of composite materials used for teeth restoration in modern dentistry. The experiment should be repeated on a broader group of resin-based composite dental materials and should take into account more light-curing units. The study could be also done in situ on a real tooth model. Practical implications: This research gives an insight into the range of temperatures that are generated during polymerization process of dental composite materials. The results of the study are of a great value during choosing the restorative composite material for particular application in the oral cavity, selecting the right light-curing-unit and adjusting the curing parameters Originality/value: The results of the study allow to conclude that the temperature values vary for each resin-based material, according to light-curing-unit type and the distance of curing seemed to have least influence on temperature changes during polymerization.

7

Influence of aging solutions on wear resistance and hardness of selected resin-based dental composites

Chladek G., Basa K., Żmudzki J., Malara P., Nowak A. J., Kasperski J.

Acta of Bioengineering and Biomechanics

|

2016

|

Vol. 18, no. 3

43--52

EN

Purpose: The purpose of this study was to investigate the effect of different plasticizing aging solutions on wear resistance and hardness of selected universal resin-based dental composites. Methods: Three light cured (one nanofilled, two microhybride) and one hybride chemical cured composites were aged at 37 °C for 48 h in distillated water, ethyl alcohol solution or Listerine mouthwash. After aging the microhardness tests were carried out and then tribological tests were performed in the presence of aging solution at 37 °C. During wear testing coefficients of friction were determined. The maximal vertical loss in micrometers was determined with profilometer. Results: Aging in all liquids resulted in a significant decrease in hardness of the test materials, with the largest values obtained successively in ethanol solution, mouthwash and water. The effect of the liquid was dependent on the particular material, but not the type of material (interpreted as the size of filler used). Introduction of mouthwash instead of water or ethanol solution resulted in a significant reduction in the coefficient of friction. The lowest wear resistance was registered after aging in ethanol and for the chemical cured hybrid composite, but the vertical loss was strongly material dependent. Conclusions: The effect of different aging solution, including commercial mouthrinse, on hardness and wear was material dependent, and cannot be deduced from their category or filler loading. There is no simple correlation between hardness of resin-based dental composites and their wear resistance, but softening of particular composites materials during aging leads to the reduction of its wear resistance.

8

Wpływ środowiska wodnego na średnicowe naprężenie rozciągające materiałów kompozytowych stosowanych w stomatologii

Prylińska-Czyżewska A., Pryliński M., Karońska K., Frączak B. A., Dorocka-Bobkowska B.

Przemysł Chemiczny

|

2015

|

T. 94, nr 11

2029-2030

PL

Określono wpływ środowiska wodnego na średnicowe naprężenie rozciągające (DTS) materiałów kompozytowych stosowanych do wykonywania tymczasowych protez stałych lub do wypełniania ubytków w tkankach twardych zęba. Badania wykazały, że wszystkie poddane ocenie materiały (poza żywicą Visalys Temp) po przechowywaniu w środowisku wodnym przez 1 tydzień wykazywały istotny wzrost wartości DTS, przy jednoczesnym zróżnicowanym stopniu chłonięcia wody wynoszącym 1,17–18,43%.

EN

Eight com. composite materials used for temporary fixed dentures or for filling cavities in hard tooth tissues were studied for H₂O sorption capacity and its effect on the diametral tensile strength. The water sorption was 1.17–18.4%. The mainly substantial increase in the strength was obsd. in all cases after the sorption.

9

Method of evaluation of degradation of bio-mechanical tooth-composite filling system

Niewczas A., Pieniak D., Niewczas A. M.

Diagnostyka

|

2010

|

nr 2(54)

51-58

EN

This paper describes a method of an enhanced life evaluation of dental fillings based on the observation of the enlargement of the marginal fissure between the filling and hard tissue of the tooth. A width of marginal fissure was considered as the functional parameter of the whole tooth-filling system in the conducted tests. In this study development of the fissure influenced by the cyclic changes of thermal loads was analyzed. The extracted human teeth were used in the tests. In which a model lesions with microhybrid composite fillings were applied. All tests were conducted on the dedicated test stand. After performance of fatigue tests, measurements of the width of marginal fissure were taken by means of SEM electron scanning microscope and optical microscope with computer image analyzer. On this basis a risk of functional unfitness of the tooth-filling system was estimated.

PL

W artykule opisano metodę przyspieszonej oceny trwałości wypełnień stomatologicznych na podstawie obserwacji rozbudowy szczeliny brzeżnej pomiędzy wypełnieniem a twardą tkanką zęba. W warunkach prowadzonych badań jako miarę zdatności czynnościowej całego systemu ząb - wypełnienie przyjęto szerokość szczeliny brzeżnej. Autorzy przeprowadzili analizę rozwoju szczeliny pod wpływem cyklicznie zmiennych obciążeń cieplnych. Do badań wykorzystano usunięte zęby ludzkie. W zębach wypreparowano modelowe ubytki i założono wypełnienia z kompozytu mikrohybrydowego. Badania zostały przeprowadzone na specjalnie opracowanym stanowisku badawczym. Po wykonaniu testów zmęczeniowych przeprowadzano pomiary szerokości badanej szczeliny brzeżnej, wykorzystując elektronowy mikroskop skaningowy SEM. Na tej podstawie oszacowano ryzyko niezdatności użytkowej układu ząb - wypełnienie.

10

Zastosowanie rozgałęzionych żywic uretanowo-metakrylowych w kompozytach stomatologicznych

Szafran M., Rokicki G., Czerwińska L., Bobryk E.

Kompozyty

|

2008

|

R. 8, nr 1

47-52

PL

Zaprezentowano wstępne wyniki badań dotyczących wpływu ilości kamforochinonu (fotoinicjator) na przebieg procesu fotopolimeryzacji oraz wpływ zawartości siarczanu baru na właściwości mechaniczne kompozytów przeznaczonych na stałe wypełnienia stomatologiczne. W celu zbadania mikrotwardości Vickersa, wytrzymałości na zginanie wykonano serię próbek kompozytowych zawierających mikro- i nanokrzemionkę. Wykonano również badanie mikrostruktury powierzchni przełomu kształtek kompozytowych w celu zbadania połączenia ceramika-polimer. Kompozyty ceramiczno-polimerowe są stosowane w stomatologii już od ponad 50 lat. Mimo to zainteresowanie nimi nie maleje. Stomatolodzy wciąż szukają materiałów, które łączyłyby dobre właściwości mechaniczne, zbliżone do amalgamatu z jednoczesną estetyką wypełnienia. Dowiedziono, że lepsze właściwości mechaniczne można uzyskać poprzez zastosowanie zarówno monomerów, zawierających ugrupowania uretanowe, jak również dzięki odpowiedniej ilości i składu proszku ceramicznego.

EN

In this study, the preliminary results of investigations concerning the influence of the amount of camphorquinone (the photoinitiator) on the photopolymerization process and the influence of barium sulphate content on the mechanical properties of the composites for dental applications were presented. In order to examin composites' properties, such as Vicker's microhardness, bending strength the samples containing micro- and nanosilica fillers as well as barium sulfate were prepared. To investigate the ceramics-polymer binding the fractures of the cured composite were analyzed. X-ray the pictures of the samples containing different amounts of BaSO4 were presented. The higher concentration of BaSO4, the larger X-ray contrast is visible. It can be noticed that the method of the powder mixing influenced X-ray contrast. Ball milling of the ceramic powder with water (ratio 1:1) leads to more homogeneous composites. The X-ray contrast of the sample with BaSO4 was compared with the reference sample (80% SiO2, 20% K3M). It can be seen that the addition of BaSO4 causes, that the mass has a better X-ray contrast. The investigation of Vicker's microhardness of composites of A series showed that optimal content of BaSO4 is 10 wt. %. However, considerable influence of the presence of BaSO4 on bending strength was observed. The bending strength of the composites falls down with the growth of the content of BaSO4. It was shown that with the increase of the amount of the initiator in the composition, the microhardness and bending strength of the composites rises. However, for higher amount of camphorquinone the color of the composites becomes more yellow.