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EN
In this study the mechanical properties of polypropylene (PP) with a small amount of TiO2, after UV-C exposure were preliminarily analyzed. The effectiveness of titanium oxide was evaluated in two alternative applications: TiO2 as the polymer filler and TiO2 as a protective outer coating. The samples were exposed to UV-C rays for 1000 hours. It was found that an addition of 5 wt.% TiO2 to PP matrix results in a 60% smaller decrease in Rg after 1000 h of exposure to UV-C than in the case of neat polypropylene. It was also found that the addition of TiO2 to the polypropylene matrix is more effective than TiO2 applied as a coating component. The Rg decrease after exposure is about 35% in this case. The research confirmed that TiO2 submicrometric particles seem to be a very good component in reducing the sustainability of polypropylene to UV radiation.
2
Content available remote Selected properties of polypropylene-BaSO4 composites after UV exposure
EN
The paper presents a preliminary study on the effect of an addition of barium sulfate (BaSO4) particles on the mechanical properties of polypropylene (PP) and an evaluation of the effectiveness of this additive in protecting the material against UV rays. Tests were carried on PP samples filled with BaSO4 powder and on samples covered with a protective coating based on BaSO4. Samples of the materials were exposed to UV-C rays for 1000 hours. After exposure, specimens were subjected to static three-point bending tests and hardness examination. Based on the obtained results, it was concluded that BaSO4 reduces the decrease in flexural strength and in hardness caused by exposure to UV-C rays by half in comparison with neat PP. The action of BaSO4 particles as a filler of PP and as a component of a coating applied on the surface of the sample results in similar anti-UV protection of the material. BaSO4 seems to be a commonly available and inexpensive anti-UV protector for plastics.
PL
Folie zawierające polilaktyd jako osnowę polimerową, montmorylonit jako napełniacz oraz poli(ε-kaprolakton) jako kompatybilizator naświetlano promieniowaniem UV-C (max 254nm) w odstępach dwu godzinnych do 16 godzin. Wpływ napełniacza oraz obecności kompatybilizatora na proces fotodegradacji analizowano przeprowadzając badania właściwości termicznych, zarówno wyjściowych materiałów jak i po różnych czasach ekspozycji na UV. Pod uwagę brano między innymi następujące parametry: stabilność termiczną, temperaturę zeszklenia czy stopień krystaliczności. Otrzymane wartości wskazują, iż wprowadzenie poli(ε-kaprolaktonu) jak i montmorylonitu powoduje wzrost stopnia krystaliczności materiałów, co jest jednym z kluczowych czynników wpływających na proces fotodegradacji. Na podstawie uzyskanych wyników stwierdzono, iż obecność napełniacza podobnie jak i kompatybilizatora poprawia odporność kompozytów polilaktydowych na działanie promieniowania UV.
EN
Films consisting of polylactide as polymer matrix, montmorillonite as filler and poly(ε-caprolactone) as compatibilizing agent were irradiated with UV (254 nm) at intervals of 2-16 hours. Effect the presence of filler and compatibilizing agent has got on photodegradation process was analyzed by examination of thermal properties of both the starting material and the material after various times of exposure to UV radiation. The following parameters were taken into account: thermal stability, temperature of glass transition as well as degree of crystallinity. Determined values indicate that the introduction of a compatibilizing agent and a nanofiller into polymer matrix increases degree of crystallinity of obtained materials. Degree of crystallinity is an important factor influencing photodegradation process. Based on obtained results it has been established that the presence of a nanofiller as well as a compatibilizing agent improves thermal stability of polylactide composites exposed to UV radiation.
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