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Poszukiwanie grzybów zdolnych do wzrostu na tworzywach polimerowych

Janczak K., Dąbrowska G., Hrynkiewicz K., Raszkowska-Kaczor A.

Przemysł Chemiczny

2014

T. 93, nr 7

1206-1209

Badano wzrost grzybów Clitocybe, Laccaria laccata, Trichoderma viride i jednego niezidentyfikowanego grzyba, wyizolowanych z gleb zdegradowanych, na foliach z polikaprolaktonu, polilaktydu, polihydroksymaślanu, polietylenu i poli(tereftalanu etylenu) przez 1–2 tygodnie w temp. 24°C. Do badania wzrostu grzybów na foliach wykorzystano skaningową mikroskopię elektronową. Najlepszym wzrostem na podłożach polimerowych charakteryzował się szczep Laccaria laccata, nie tylko na polikaprolaktonie, lecz także na foliach z polietylenu i poli(tereftalanu etylenu).

Clitocybe, Laccaria laccata, Trichoderma viride and unidentified fungi strain were isolated from degraded soils and grown on polycaprolactone, polylactide, polyhydroxybutyrate, polyethylene and poly(ethylene terephthalate) films at 24°C for 1–2 weeks. The growth of fungi was obsd. by scanning electron microscopy. Laccaria laccata showed the highest growth, not only on polycaprolactone but also on polyethylene and poly(ethylene terephthalate) films.

Polyolefin oxo-degradation accelerators – a new trend to promote environmental protection

Cichy B., Kwiecień J., Piątkowska M., Kużdżał E., Gibas E., Rymarz G.

Polish Journal of Chemical Technology

2010

Vol. 12, nr 4

44-52

The paper presents the results of the tests on the preparation of iron (III) stearate – the most prominent oxo-biodegradation agent for polyolefinic plastics. The process chosen for testing was the double precipitation process, using stearic acid alkalised with soda lye and iron (III) chloride or iron (III) sulphate. A number of iron (III) stearate preparation methods described in the literature were tested and an analytical procedure for monitoring the process was developed using both the classical and instrumental techniques. FTIR spectroscopy is the most useful technique for the product quality control and identification. During the study the characteristics of the proper product were also determined using the DSC methods. Microscopy and laser diffraction particle size analysis were applied to determine the size of the precipitated product grains. An application sample of the product obtained by the double decomposition method from iron (III) sulphate as the iron carrier has successfully passed the application tests in the polyethylene packaging film.