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Co-pyrolysis of PCB and cotton stalk: Towards enhanced phenol production and debromination of pyrolysis oil

Prajapati Sonalben B., Gautam Alok, Gautam Shina

Chemical and Process Engineering

2022

Vol. 43, nr 2

203–-216

With advancing technology, printed circuit board (PCB), one of the most important components of e-waste, has become a source of pollution due to an ineffective waste management system. This problem can be solved by converting PCB waste into a valuable product which will emerge to maximize the renewable energy supplies. In this aspect, co-pyrolysis is advantageous in both simple and successful in producing high-quality pyrolysis oil. In this paper, cotton stalk (CS) as biomass was used and pyrolysis of PCB, CS, and a mixture of both in 1:1 have been carried out. CS has a good combustibility at 500 C which was chosen for the pyrolysis reaction in a fixed bed reactor for slow pyrolysis. The pyrolytic oil was analysed by GC–MS and FTIR. The results indicate that there is an increase in oil yield from 19.6% to 27.5% by weight and phenol and phenolic compounds in oil of co-pyrolysis from 60.94% to 76.82% compared to literature available. There is an increase in bromine solidification in char by 25% with a mixture of CS and PCB compared to CS and PCB individually which is much higher than literature data. To the best of the authors’ knowledge, co-pyrolysis of PCB:CS has been attempted first time and debromination of oil was found excellent in the present work.

Nature Cellulose Fibre Extracted from Different Cotton Stalk Sections by Degumming

Li L., Zhao L.

Fibres & Textiles in Eastern Europe

2015

Vol. 23, no. 6 (114)

37--40

Bast fibres are important because they have biodegradable and eco-friendly characteristics. In this paper, natural cellulose fibre extracted from cotton stalk by degumming was investigated. On the basis on the chemical propertiess of cotton stalk bark, a cotton stalk was divided into three sections before fibres were extracted. Through an orthogonal experiment, the extracting conditions of fibres from different sections were obtained. The flexibility and linear density of the fibres extracted were then tested, and the morphology of the fibres was observed by SEM. It was shown that the flexibility and fineness of fibres from the different sections were various. The singular unit fibrel morphology of fibres from different sections had a visible difference.

Włókna łykowe odgrywają istotną rolę ponieważ są biodegradowalne i przyjazne środowisku. Badano naturalne celulozowe włókna ekstrahowane z łodyg bawełny poprzez odgumowywanie. Na podstawie właściwości chemicznych łodygę bawełny dzielono na trzy części przed przeprowadzeniem ekstrakcji. Doświadczalnie określono warunki ekstrakcji dla poszczególnych wyodrębnionych sekcji. Badano elastyczność i masę liniową, oraz za pomocą SEM morfologię. Stwierdzono, że zarówno elastyczność jak i masa liniowa włókien jest różna dla różnych sekcji łodygi. Morfologia jednostkowych włókien wyekstrahowanych różniła się widocznie dla wszystkich trzech części łodygi.