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EN
This study aims to leach copper from chalcopyrite and optimizing the leaching process, using the response surface methodology (RSM). The RSM, a D-optimal design with four factors in three levels was employed to evaluate the effect of particle size, temperature, silver-coated pyrite to chalcopyrite ratio and redox potential parameters on the copper extraction efficiency. A quadratic model was then proposed by the RSM to correlate leaching variables. The tests results indicated that the model was significant with the experimental data at a correlation coefficient (R2) of 0.96. The most important parameters of copper extraction efficiency were particle size and silver-coated pyrite-to-chalcopyrite ratio, and also the squared term of particle size (A2), temperature (B2) and redox potential (D2). In addition, the interaction between redox potential and silver-coated pyrite-to-chalcopyrite ratio (CD) was significant. It was shown that the finer the particle size the faster the leaching rate of copper. It was also indicated that by increasing silver-coated pyrite to chalcopyrite ratio of 6:1 copper recovery increased. The maximum recovery of copper (71%) was obtained for the particle size of -38 μm, 70 °C, 420 mV of redox potential, silver-coated pyrite-to-chalcopyrite ratio of 6 and leaching time of 8 hours.
EN
Copper flotation waste, generated as a byproduct of pyrometallurgical copper production, contains a significant amount of Cu together with trace amounts of other toxic elements such as Fe, Sn, Sb, As, and Pb. It is usually disposed in uncovered tailing ponds in the vicinity of a copper smelter plant. Heavy metals released into the water and soil can cause a number of environmental problems. The amount of copper in copper flotation waste is high enough to be extracted economically using appropriate methods. In this study, the leaching characteristics of copper flotation waste from the Bor Copper Mine, Serbia, were investigated to assess the feasibility of copper extraction.
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