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1

Badania spektralne i wiązania jonowego w serii kompleksów rutenu(II) i miedzi(I)

Kong Jianfei, Li Mingmei, Shi Yun, Zhang Lihu, Yang Guochun

Przemysł Chemiczny

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2021

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T. 100, nr 10

963--968

PL

Zsyntetyzowano serię oksa- lub oksa-tia-koronowych diiminokompleksów Ru(II) i Cu(I) i zbadano ich absorpcję oooelektronową oraz właściwości spektralne, a także zdolność wiązania kationów metali alkalicznych, ziem alkalicznych i metali przejściowych. Zmiany spektralne zachodzące po dodaniu jonów metalu gościa monitorowano za pomocą spektroskopii elektronowej absorpcyjnej i emisyjnej, wyznaczając stałe stabilności kompleksowania 1:1 w roztworach aprotycznych i protofilowych. Kompleksy oksa-tia-koronowe C₄₀H₄₀F₁₂N₆O₂P₂RuS₃ (II) i C₅₆H₅₄BF₄N₂O₂P₂S₃Cu·CH₂C₁₂ (III) wykazywały wyższą zdolność wiązania jonów metali przejściowych niż jonów metali alkalicznych i ziem alkalicznych, podczas gdy kompleks C₄₀H₄₀F₁₂N₆O₅P₂Ru (I) nie wykazywał żadnej zdolności wiązania kationów. Tak więc kompleksy z miękkimi donorami w cząsteczkach koronowych były odpowiednie dla miękkich kationów gościa, szczególnie dla kationów Hg(II).

EN

Three oxa- or oxa-thia-crown diimine complexes of Ru(II) and Cu(I) were synthesized and studied for electronic absorption spectra and for binding ability with alk., alk. earth and transition metal cations. The spectral changes triggered upon addn. of guest metal ions were monitored by electronic absorption and emission spectroscopies and thus the stability constants for 1:1 complexation were detd. in aprotic and protophilic solns. The oxa-thia-crown-containing complexes C₄₀H₄₀F₁₂N₆O₂P₂RuS₃ and C₅₆H₅₄BF₄N₂O₂P₂S₃Cu·CH₂Cl₂ exhibited higher binding performance towards transition metal ions than towards alkali or alkaline earth metal ions. The complex C₄₀H₄₀F₁₂N₆O₅P₂Ru did not show any cation-binding ability. Thus, the complexes with soft donors in the crown moieties were applicable for soft guest cations especially for Hg(II) ones.

2

63Cu and 31P Nuclear Magnetic Resonance for Characterization of Cu(I) Complexes with P-Donor Ligands

Szymańska I.

Polish Journal of Chemistry

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2006

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Vol. 80, nr 7

1095-1117

EN

The analysis of the 63Cu and 31PNMR resonances and the spin-spin coupling patterns for elucidation of the Cu(I) phosphines complexes geometry and ligands' coordination modes in solutions are reviewed. The influences of the steric and electronic properties of P-donor ligands and the dynamic processes in solution on the 63Cu and 31P NMR spectra of Cu(I) complexes are discussed.

3

Synthesis and Characterization of Ionic Cu(I) Perfluorocarboxylate Compounds with 1,4-Bis(diphenylphosphino)butane

Szymańska I., Pazderski L., Kucharek R., Szłyk E.

Polish Journal of Chemistry

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2005

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Vol. 79 / nr 11

1705-1711

EN

A series of ionic Cu(I) perfluorocarboxylate compounds with 1,4-bis(diphenyl - phosphino)bu tane (dppb) of gen eral formula [Cu(dppb)2](RCOO), where R = C2F5, C3F7, C4F9, C6F13, C8F17, was prepared and characterized with MS, IR and 1H, 13C, 19F, 31P NMR spectroscopy. The studied species contained monomeric, bis-chelated [Cu(dppb)2]+ cations and uncoordi nated RCOO- anions. The Cu(I) coordi nation of the diphosphines resulted in slight high-frequency shifts of the 31P NMR resonances of the equivalent phosphorus atoms.

4

New Copper(I) Perfluorinated Carboxylates Complexes with Bis(diphenylphosphine)methane

Szłyk E., Kucharek R., Szymańska I.

Polish Journal of Chemistry

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2001

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Vol. 75, nr 3

337-344

EN

Copper(I) perfluorinated carboxylates complexes with bis(diphenylphosphine)methane (dppm) of general formula [Cu2(ž-dppm)3(RCOO)2] dppm, whereR=C2F5, C4F9, C6F13, C8F17, C9F19, have been prepared and characterized by vibrational, 31P CPMASNMRand 13C CPTOSSB NMR mass spectra in the solid state. 1H, 13C, 19F NMR and variable temperature 31P NMR spectra were measured in solution. Temperature variable 31P NMR spectra revealed at least three dimeric species in equilibrium. IR and mass spectra analyses suggest dimeric complexes with three bridging diphosphines and monodentate carboxylates in the solid state.

5

Copper(I) Nitrate P-Complexation : Synthesis and Crystal Structure of [{CH2=CH-CH2-NHC(NH2)2}Cu(NO3)2] Compound

Filinchuk Y., Mys'kiv M.

Polish Journal of Chemistry

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2000

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Vol. 74, nr 7

927-933

EN

By alternating-current electrochemical synthesis, a crystalline P-complexe has been obtained using copper(II) nitrate and allylguanidine in butanol-2 solution and copper-wire electrodes. A single crystal of the compound was X-ray structurally characterized.

6

Synthesis and Crystal Structure of Copper(I) Chloride P-Complex with 1-Allylbenzotriazole of CuCl.C6H4N3(C3H5) Composition

Goreshnik E.

Polish Journal of Chemistry

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1999

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Vol. 73, nr 8

1253-1258

EN

By alternating-current electrochemical synthesis crystals of CuCl.C6H4H3(C3H5) P-complex (I) have been obtained and structurally investigated. Due to the coordination of Cu(I) atoms through the nitrogen atom and olefinic group of the same molecule, organometallic chains appear. bridged Cl atoms combine these chains into a three-dimensional framework.

7

Cation of N-Allylbenzothiazolium as a P-Ligand in Copper(I) Halide Complexes: Synthesis and Crystal Structure of [C7H5NS(C3H5)]+.CuCIcl2.H2O and [C7H5NS(C3H5)]+.CuCl1.06Br0.94.H2O Compunds

Goreshnik E., Mys'kiv M.

Polish Journal of Chemistry

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1999

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Vol. 73, nr 8

1245-1252

EN

By alternating-current electrochemical synthesis crystals of [ ] P-complexes have been obtained and structurally characterized. Owing to the cationic form, the ligand is coordinated to Cu atom only through the C=C bond. Due to the bridge role of X(2) atom [X=Cl(I) or statistic mixture Cl, Br (II))}, cyclic fragments Cu2X2 appear.