The purposes of the current research were to deposit the silver nanoparticles on the surface of a textile woven fabric and evaluate their dyeing performance and antibacterial activity. The synthesis of silver nanoparticle (Ag°) is done by the in situ method. Strong alkali is used to improve functionality of cellulose before the application of silver nitrate salt (AgNO3). The silver nanoparticle is formed by reduction of ascorbic acid. Various instrumental analyses are done to prove the formation of nanoparticles on the fabric surface. The morphology of nanodeposited fabric is characterized by using scanning electron microscope (SEM), elemental composition is done by energy dispersive spectroscopy, and crystallinity of nanoparticles is obtained by X-ray diffraction (XRD). Nanodeposited fabric is then dyed with direct dyestuff (Direct Red-89). Fourier transform infrared spectroscopy analysis is done to explore the bonding phenomena of un-dyed and dyed fabrics. The dyeing performance and antibacterial activity are examined on the colored fabric to investigate the dyed fabric quality after nanoparticle deposition. Results demonstrate the improvement of 54% of color strength and 11% of dye exhaustion with excellent antibacterial activity.
Cellulase has the ability to remove fuzz-fibres from cellulosic textiles, which endows fabric with a glabrous appearance and soft handle. In this paper, the combined uses of bio-polishing and reactive dyeing in one bath were carried out, aiming at shortening the treatment time and reducing the overall consumption of water and energy as well. The properties of cotton fabrics before and after the combined treatments were investigated, including the colour strength, colour fastnesses and tearing strength. The results indicated that the colour fixing agent of soda had noticeable inhibiting effects on cellulase activity. Meanwhile reactive dyes might react with cellulase proteins under alkaline conditions, resulting in decelerating influences on the dye-fibre covalent reactions. The acceptable one-bath process consisted of bio-polishing and dyeing of cotton in neutral solution, followed by dye fixation under alkaline conditions. Compared to polishing and dyeing in two baths, the one-bath method endowed fabric with a bit lower colour strength.
PL
Celulaza ma zdolność do usuwania włosków zmechacenia z tekstyliów celulozowych, co pozwala na osiągnięcie gładkiej powierzchni o delikatnym chwycie. W pracy badano sumaryczny efekt biopolerowania i reaktywnego barwienia przeprowadzanych w jednej kąpieli. Metoda ta ma na celu skrócenie czasu obróbki i zredukowanie ogólnego zapotrzebowania na wodę i energię. Badano właściwości tkanin bawełnianych przed i po obróbce. Między innymi badano nasycenie kolorem, trwałość koloru i wytrzymałość na rozrywanie. Wyniki wskazują, że soda jako środek utrwalający kolor ma zauważalny wpływ na hamowanie działania celulazy. Porównując metodę równoczesnego polerowania i barwienia z metodą, gdzie obydwie obróbki stosowane są indywidualnie stwierdzono, że w metodzie równoczesnej obróbki uzyskuje się nieco niższe nasycenie koloru.
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Nylon (6.6) fabric was dyed with Indigo dye using an exhaust technique at different pH values. At different pH values different forms of indigo existed in solution, each one having a different substantivity for the fibre. The non-ionic form had the highest, whilst the Ionic ones had relatively less substantivity. The fibres could best be dyed in the acidic to slightly alkaline pH range. The Chemistry of the dyebath and fibre were considered, in order to explain the effect of pH on colour strength. Hydrogen bonding and ionic interactions seemed to be the main reason for the exhaustion of dye onto nylon fibre. Hydrogen bonding occurred between the hydroxyl groups and amide groups, while ionic interactions worked at low pH values between the ionized and end-amino groups of the dye and fibre respectively.
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