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Adsorption method of purification of stocks from chromium(III) ions by bentonite clays

Soloviy Christina, Malovanyy Myroslav, Palamarchuk Olga, Trach Iryna, Petruk Halyna, Sakalova Halyna, Vasylinych Tamara, Vronska Nataliya

Journal of Water and Land Development

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2021

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no. 48

99--104

EN

The process of sorption of chromium(III) ions with a stationary sorbent layer of bentonite clays was investigated. The main advantages of using bentonites in water purification technologies are described: powerful geological reserves, cheap process of rock extraction, easy preparation for transportation and use, possibility of using waste sorbents in other technologies that is why there is no need in costly regeneration. The influence of various factors (process duration, an adsorbent layer) on the degree of wastewater purification from chromium ions, the effect of pumping speed on the dynamic capacity of the sorbent was studied and the effective volume was determined. The adsorption efficacy increases with the increase of the adsorbent layer, what can be explained by the development of the active sorption surface. As the initial concentration of chromium ions increases, the time of appearance of the first traces of the contaminant at the exit of the column increases, as well as the total time to channeling. The results of the studies indicate a higher adsorption capacity of modified bentonite with respect to Cr3+ ions compared to its natural formula. The cleaning efficacy of the solution with a concentration of chromium ions of 0.5 g∙dm–3 is increased by 5% when using 15 g of modified bentonite and 6,5% in the case one uses 20 g compared to the natural form.

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Adsorption Extraction of Chromium Ions (III) with the Help of Bentonite Clays

Malovanyy Myroslav, Palamarchuk Olga, Trach Iryna, Petruk Halyna, Sakalova Halyna, Soloviy Khrystyna, Vasylinych Tamara, Tymchuk Ivan, Vronska Nataliya

Journal of Ecological Engineering

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2020

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Vol. 21, nr 7

178--185

EN

This work is dedicated to the development of scientific technologies of wastewater purification of different industrial enterprises from chrome ions through adsorption with the help of bentonite from Cherkasy field under dynamic conditions. The prospects and efficacy of bentonite clays application for wastewater purification are confirmed by their advantages over other sorbents, that is: they win in accessibility, cost, and possibility of regeneration and multiple applications. The level of wastewater purification during adsorption with a stationary sorbent layer under static conditions and under conditions of perfect mixing at different concentrations of chromium ions (III) and quantities of the dosed sorbent was determined. The significant difference in the purification level ranges from 70–87% and is more dependent on the stock concentration of chromium ions. It was found that the purification time of the same volumes of solutions for low concentrations is almost twice shorter under constant stirring, and of the same level at the stock concentrations of 1500 mg/dm3. The technological schemes of wastewater purification from the heavy metal ions contamination were developed.

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The variability of pollution load of organic, biogenic and chromium ions in wastewater inflow to the treatment plant in Nowy Targ

Bugajski P. M., Nowobilska-Majewska E., Kurek K.

Journal of Water and Land Development

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2017

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no. 35

11--17

EN

The aim of the study was to analyze the mean daily wastewater load from the corporate wastewater treatment plant in Nowy Targ. The study analyzed the wastewater load expressed by BOD5, COD, total nitrogen (Ntot), total phosphorus (Ptot) and chromium ions (Cr). The study was conducted from 2006 to 2016, in which 591 samples of raw wastewater were collected and analyzed in a control well before the treatment plant with a mean of 4 times a month. The scope of research in the analytical part covered the variability of wastewater loads in individual years and determined the characteristic values of mean daily load in particular months. Mean daily wastewater load for BOD5 – 7 053 kg·d–1 for COD – 23 437 kg·d–1 for total nitrogen – 1 464 kg·d–1 for total phosphorus – 197 kg·d–1 and for chromium ions – 129 kg·d–1. For each of the analyzed index, it was found that in the each months mean daily wastewater load in raw wastewater is variable. In the analyzed period the mean daily discharged wastewater oscillated within 13 924 m3·d–1, which accounted for about 66% of the projected load.

PL

Celem pracy jest analiza wartości średnich dobowych ładunków zanieczyszczeń dopływających w ściekach surowych do zbiorczej oczyszczalni w Nowym Targu. W pracy poddano analizie zanieczyszczenia wyrażone wskaźnikami BZT5, ChZT, azotu ogólnego (Nog), fosforu ogólnego (Pog) oraz ładunkiem jonów chromu (Cr). Badania prowadzono w okresie od 2006 do 2016 roku, w którym pobrano i poddano analizie 591 próbek ścieków surowych pobranych w studzience kontrolno-pomiarowej przed oczyszczalnią ze średnią częstością 4 razy w miesiącu. W części analitycznej zakresem badań objęto zmienność ładunków zanieczyszczeń w poszczególnych latach oraz określono charakterystyczne wartości średniego dobowego ładunku w poszczególnych miesiącach. Na podstawie przeprowadzonej analizy stwierdzono, że średni dobowy ładunek wyrażony BZT5 wyniósł 7 053 kg∙d–1, ChZT – 23 437 kg∙d–1, ładunek azotu ogólnego – 1 464 kg∙d–1, fosforu ogólnego – 197 kg∙d–1 i jonów chromu – 129 kg∙d–1. W odniesieniu do każdego z analizowanych wskaźników stwierdzono, że w poszczególnych miesiącach średni dobowy ich ładunek w ściekach surowych jest zmienny. W analizowanym okresie średni dobowy dopływ ścieków oscylował w granicach 13 924 m3∙d–1, co stanowiło około 66% obciążenia projektowanego.

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Badania ekstrakcji jonów chromu (III) kwasem antranilowym w układach siarczanowych

Kalembkiewicz J.

Zeszyty Naukowe Politechniki Rzeszowskiej. Chemia

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1998

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z. 15 [169]

17-25

PL

Zbadano ekstrakcję jonów chromu (III) w układach dwufazowych typu kwas antranilowy-toluen-woda (H+, Na+, SO2-/4); I=0,5. Określono warunki wydzielania jonów chromu (III) w badanych układach, podano skład kompleksów chromu (III) w fazie organicznej i opisano równaniami równowagi ekstrakcyjne.

EN

It was carried out the extraction of chromium (III) ions in two-phase systems: anthranilic acid-toluene-water (H+, Na+, SO2-/4); I=0,5. The conditions of separation of chromium(III) ions in examined systems were determined. The composition of chromium (III) complexes in organic phase and extraction equilibriums were described.