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Influence of hydrate formation and concentration of salts on the corrosion of steel 20 pipelines

Poberezhny Lubomyr, Chudyk Ihor, Hrytsanchuk Andrii, Mandryk Oleg, Kalyn Tetyana, Hrytsuliak Halyna, Yakymechko Yaroslav

Management Systems in Production Engineering

2020

nr 3 (28)

141--147

One of the ways to increase natural gas production is to conserve and/or intensify existing wells with their subsequent development. They are characterized by a high content of highly mineralized water, which leads to an increased risk of hydrate formation and internal corrosion. The issue of the formation of gas hydrates in industrial pipelines, which is a major problem for the exploitation of industrial gas pipelines, requires considerable attention to be made to exclude emergency situations. The main task of the study – to determine the effect of hydrates on the corrosion of the pipeline in order to prevent emergencies. A technique for studying the effect of hydration on the corrosion of pipelines has been developed. The combined analysis of the corrosion behavior of pipe material in aggressive media of chloride type was done. According to the results of corrosion-mechanical tests, regularities of joint action of mechanical stresses, concentration of chlorides and hydrate formation on the speed and localization of corrosion processes are established.

Solvent extraction of zinc(II) ions from chloride media by 4-pyridylketoximes

Parus A.

Chemistry, Environment, Biotechnology

2016

Vol. 19

93--100

Three homologues of 4-pyridylketoximes were synthesized and used as potential ligands for zinc(II). Their solvent extraction behaviors for zinc(II) in chloride solutions were investigated using CHCl3 as the diluent. The effect of different variables on the extraction of zinc(II) ions, such as the pH of aqueous phase, metal and chloride ions as well as the type of oxime, has been investigated. Results indicated that 4-pyridylketoximes could extract zinc(II) ions from chloride solutions and the extraction depended on the concentrations of the ligand, chloride ions and hydrochloride acid. Slope analysis confirmed that the 4-pyridylketoximes ligands form a 1:2 complex with zinc(II) in both chloride/nitrate and chloride/perchlorate solutions. After extraction, zinc(II) could be easily stripped from organic phase with water.