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Wpływ rodzaju powierzchni próbki na współczynnik dyfuzji jonów chlorkowych w betonie

Kuziak Justyna, Kryszczyński Artur

Przegląd Budowlany

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2020

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R. 91, nr 6

32--35

PL

W pracy przedstawiono wyniki badań wyznaczania efektywnego współczynnika jonów chlorkowych w betonie o w/c = 0,3. Próbki betonu po 14 miesiącach twardnienia poddano 39-41 dniowemu wnikaniu jonów chlorkowych z 3% roztworu NaCl. Badania przeprowadzono na trzech rodzajach powierzchni: powierzchni górnej, powierzchni bocznej i ciętej. Największy efektywny współczynnik dyfuzji jonów chlorkowych (4,7⋅10-12 m2/s) otrzymano w przypadku wnikania chlorków do betonu od powierzchni formowanej, nieco mniejszy dla powierzchni zacieranej (4,2⋅10-12 m2/s), a najmniejszy (1,2⋅10-12 m2/s) dla powierzchni ciętej.

EN

The results of tests for determining the chloride ion effective diffusion coefficient in concrete with w/c = 0.3 were presented. Concrete samples after 14 months of hardening were subjected to 39-41 days ingress of chloride ions from 3% NaCl solution. The tests were carried out on three types of surfaces: top, side and sawn surface. The highest chloride ion effective diffusion coefficient (4,7⋅10-12 m2/s) was obtained in the case of chloride penetration into the concrete from the side surface, slightly smaller for the top surface (4,2⋅10-12 m2/s) and the smallest (1,2⋅10-12 m2/s) for the sawn surface.

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Evaluation of factors affecting bulk chlorine decay kinetics for the Zai water supply system in Jordan. Case study

Saidan M. N., Rawajfeh K., Nasrallah S., Meric S., Mashal A.

Environment Protection Engineering

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2017

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Vol. 43, nr 4

223--231

EN

Chlorine decay behavior is significantly variable since it depends on the quality of water and the condition of a distribution system. The effect of various parameters on the bulk chlorine decay kinetics in water samples collected from the Zai water treatment plant in Jordan has been examined. These parameters are reaction time, temperature, TOC, and free chlorine dose. An empirical equation describing the abovementioned effects has been derived. The general trend of chlorine decay decreases upon time and can fairly be represented by first-order decay kinetics. An increase in the value of temperature and TOC parameters has proportional effects on the decay of bulk chlorine. However, the data show that the decay constants were found to be inversely proportional to the initial chlorine concentration. A general correlation for the calculation of bulk chlorine decay rate constant as a function of the parameters in question of this study has been proposed. Consequent predictions are in good agreement with the observed results in this study.

3

Zmiany stężenia jonu chlorkowego w Wiśle w Krakowie

Motyka J., Juśko J., Kasprzak A.

Przegląd Geologiczny

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2015

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Vol. 63, nr 10/2

963--966

EN

The paper presents the study of chloride concentrations in the Vistula river in Krakow, performed from 1990'. Growth of black coal mining in the Upper Silesia and the D¹browa Basin had significant impact for water quality in the Vistula river. After Second World War, year by year, the chloride concentration was being raised, in the end of 1970' reached 30g/l. Saline mine water discharge led to change hydrochemical water type from Ca–HCO3 to Na–Cl. Due to Polish Environment Law, concentrations of that ion was reduced, mostly to value below 1g/dm3. The water of the Vistula river has been sampled almost every week. The studies showed variability of chloride concentrations. Rate of water salinity depend on amount of the mine water discharge and water flow in the Vistula river. No cooperation between particular mines contributed to stochastic, variable salinity level.

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Determination of leaching parameters for the recovery of platinum group metals from secondary materials

Lillkung K., Aromaa J., Forsen O.

Physicochemical Problems of Mineral Processing

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2013

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Vol. 49, iss. 2

463--472

EN

The leaching parameters for the recovery of platinum group metals were investigated with potentiostatic measurements using wire electrodes. The dissolution rates of Pt, Pd and Rh were measured in concentrated NaCl solution. The parameters inspected were the temperature, redox potential and chloride content. Measurements were done at temperatures 25–94 °C using four different NaCl concentrations, 62.5–250 g/l. Measurements were done at potentials of 950–1250 mV vs. SCE for Pt and Rh and 380–470 mV vs. SCE for Pd. Although higher temperature, potential and chloride content generally increased the dissolution rate, the effect was found to be nonlinear and slightly different for different metals. Based on the results, strongly oxidizing conditions are needed for the leaching process in order to achieve reasonable dissolution rates.

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Badania wpływu środowiska chlorkowego na trwałość konstrukcji żelbetowej hali przemysłowej

Kubiak J., Łodo A., Michałek J.

Przegląd Budowlany

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2010

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R. 81, nr 7-8

63-69

PL

Przedstawiono wyniki badań zawartości chlorków w otulinie zbrojenia żelbetowych i sprężonych elementów prefabrykowanej konstrukcji hali odlewni aluminium. Opisano sposób doboru funkcji dyfuzji chlorków w betonie (wynikających z prawa Ficka) aproksymujących wyniki badań doświadczalnych. Na podstawie dobranych funkcji określono okresy trwałości głównych elementów konstrukcyjnych hali eksploatowanej w środowisku chlorkowym.

EN

The results of investigations of the chloride content of a concrete covering of reinforced and prestressed concrete elements of the aluminum-casting factory structure are presented. The method of the selection of chloride diffusion function in concrete (on the basis of Fick law) was described. The theoretical curves approximate the experimental curves. On the basis of the selected functions the durability of the main structural elements of industrial hall in chloride background was estimated.