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Content available remote A Novel Foam Coating Approach to Produce Abrasive Structures on Textiles
EN
Abrasive materials are classified as paper, nonwoven, or plastic-based multilayer structures, which are used for different kinds of surface finishing. Currently, the production of abrasive structures on textiles is carried out by spraying a slurry of binder and abrasive particles, e.g., Al2O3 or SiC, with subsequent drying and curing of the binder. The drawback of this production method is the poor runnability of the spraying process. Even small variations in the process parameters may lead to an uneven coating. Therefore, a novel coating approach was developed to produce abrasive structures with foam coating on textile substrates. The foam coating method, which is commonly used in the textile industry, has the potential to produce an even coating layer. The runnability and reliability of the foam coating process are good even with high solids. From a workplace safety perspective, another advantage of foam coating is that there are no airborne particles during the coating process. A polyamide woven cloth was foam coated with an aqueous slurry containing abrasive grains (SiC), a water-based UV-curable acrylate binder, and cellulose nanocrystals (CNCs) to adjust the slurry rheology. Stable abrasive-binder foams were generated from the slurries even at high solids of 50% using an anionic foaming agent. The cloth was foam coated and dried, and the resin was cured with a LED-UV lamp on a pilot scale. It was observed that without the addition of CNC the foam did not stay on the surface of the cloth after coating. CNC acts as a rheology modifier and co-binder, which prevent the foam from penetrating deeper into the pores of the cloth. CNC also acted as a dispersing agent: the slurry was effectively stabilized by the CNC to prevent sedimentation of the abrasive grains. An organic solvent-free composition was introduced by combining CNC with a water-based UV-resin.
2
Content available remote Self-ordered cellulose nanocrystals and microscopic investigations
EN
Cellulose nanocrystals were extracted from cotton. The cellulose nanocrystals made a self-assembly structure when dried under slow conditions, as it was revealed by the characterization made to the material. The AFM images of the nanocrystals showed that they had a changing local orientation, pointing in a preferred direction that underwent a periodic change. This periodic change resembles the orientation of a chiral nematic phase. The TEM images showed that the nanocrystals had a rod-like appearance with average length size of 98.5 nm and a diameter of 4.7 nm. The TEM characterization showed the nanocrystals with more details than AFM. In this paper, the self-assembling of CNC was observed by AFM, and further investigations were done by TEM, deconvoluting the process of CNC nanorods aggregation.
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