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O sposobach produkcji metanolu oraz wodoru z biogazu

Zając Grzegorz, Maj Grzegorz, Krzaczek Paweł, Nazimek Dobiesław

Przemysł Chemiczny

2022

T. 101, nr 8

553--558

Przedstawiono różne technologiczne możliwości otrzymywania komponentów do syntezy ciekłych biopaliw, jak również otrzymywania metanu o czystości 99,9%. Ponadto opisano proces produkcji wodoru w reakcji reformingu parowego metanu oraz otrzymywania metanolu w procesie sztucznej fotosyntezy.

A review, with 45 refs., of the use of biogas from CH₄ fermentation of organic matter for the production of MeOH. The process of direct MeOH synthesis from CH₄ and the method of processing CO₂ present in post-reaction gases to MeOH by means of artificial photosynthesis were discussed. The selective sepn. of CH₂ from biogas as well as steam reforming of biomethane in order to obtain biohydrogen were presented.

Activity of monolithic Pd/Al2O3 catalysts in the combustion of mine ventilation air methane

Kucharczyk B.

Polish Journal of Chemical Technology

2011

Vol. 13, nr 4

57-62

The activity of Pd/Al2O3 catalysts increases when Pd content is increased from 1% to 2%. Among these catalysts, 2%Pd/Al2O3 shows the highest methane combustion activity. In a reduced form, the catalyst displays a higher activity than in the oxidized form. 24-hour ageing at 600oC to 800oC lowers the catalytic activity of 2%Pd/Al2O3 due to Pd crystallite sintering. After 110-hour oxidation of 1% methane in air over 2%Pd/Al2O3, conversion decreases from 100% to 88%. Upon reduction with hydrogen (performed after 24-hour ageing at 700oC and 110-hour methane oxidation), the 2%Pd/Al2O3 catalyst regains its initial activity. The high activity of Pd catalysts renders them suitable for methane removal from coal mine ventilation air at high gas fl ow velocities and temperatures lower than 600oC.

Catalysts for the utilization of methane from the coal mine ventilation air

Stasińska B., Machocki A.

Polish Journal of Chemical Technology

2007

Vol. 9, nr 3

29-32

The paper indicates coal mines as the source of permanent emission of low-concentrated gases, which have increased the greenhouse effect. This paper proposes the catalytic oxidation of methane as the solution to the problem of methane utilization when its concentration in the air is insufficient for flame combustion. The studies which have been conducted for many years enabled finding the active oxide and metallic catalytic systems for the reaction of methane oxidation. For the utilization of gases with low-concentrated methane, using the low-temperature catalysts, especially palladium catalysts, seems to he economically well-justified. Depending on technological solutions it can be considered as the method for methane utilization or as an environmentally friendly way for the generation of electric and thermal energy.