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1 Polish Journal of Chemistry

1 2004

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New Reactions of Thiocyanatobismuthates(III) with Organic Compounds. II. Reactions of Tetrathiocyanatobimuthates(III) with Monocarboxylic Acids Salts Containing an Aromatic Ring

Cichecka M., Cygański A.

Polish Journal of Chemistry

2004

Vol.78 /nr 11-12

2037-2045

Our previous work [1] presented the reactions of caesium tetrathiocyanatobismuthate( III) with the solutions of sodium salts in aliphatic monocarboxylic acids. In this study the still unreported reactions of Cs[Bi(SCN)4] with solutions of sodium benzoate, salicylate and anthranilate, and those of Rb[Bi(SCN)4] with sodium salicylate solution are treated. The chemical, XRD, IR and thermal analyses of the reaction products were carried out. The composition of the product depends on the type of the ligand. In the case of benzoate in the solid phase, only one complex compound, Cs2Na[Bi(SCN)6] is formed, whereas the salicylate and anthranilate form two complex bismuth compounds, Cs2Na[Bi(SCN)6] and BiX3 (X - a salicylate or anthranilate anion) or BiX3.NaX.