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Azoles. Part 46 [1]. Uncommon Products from the Reactions of Some Nitroazoles with Tertiary Carbanions

Bernard M.

Polish Journal of Chemistry

2001

Vol. 75, nr 10

1465-1474

Some unusual products, like dimers, rotamers and ketone, were isolated from the reaction mixtures of vicarious nucleophilic substitution, involving nitroazoles and tertiary carbanions. Possible pathways of their formation are discussed.

Vicarious Nucleophilic Substitution of Hydrogen in 2,4-Dinitroanilines and Cyanonitroanilines

Mąkosza M., Voskresensky S., Białecki M., Kwast A.

Polish Journal of Chemistry

1999

Vol. 73, nr 12

1969-1977

Orientation of the VNS reaction in nitroaniline derivatives is mostly governed by the conjugation between the nitro groups and the amino group, which could be also deprotonated under the reaction conditions.

Oxidative Nucleophilic Substitution of Hydrogen in Nitroarenes : a Short Review

Mąkosza M., Staliński K.

Polish Journal of Chemistry

1999

vol. 73 nr 1

151-161

Selected examples of oxidative nucleophilic aromatic substitution in nitroarenes are discussed with emphasis on the authors results. Generalization of this process is attempted.