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EQCM study of charge transfer during cadmium underpotential deposition on platinum electrodes from acidic aqueous solutions

Daujotis V.

Polish Journal of Chemistry

1998

Vol. 72, nr 11

2432-2439

The potential dependence of the formal partial charge number for cadmium(II) underpotential deposition (upd) on platinum was obtained, using electrochemistry and piezoelectric microgravimetry. The comparison of this dependence with the formal partial charge number, calculated on the basis of earlier proposed mechanism of cadmium(II) upd, supports this mechanism, according to it the electrosorption valency for the cadmium(II) adsorption on platinum equals 1 and 2.