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1
Content available remote The thermal analysis and derivative bronzes cast to plaster moulds
EN
It plaster moulds gets casted the alloys of following metals: Al, Cu, Ag, Au in precise and artistic founding. The investigation of the crystallization of bronzes in hot plaster moulds the method of the thermal analysis and derivative (TDA) was not realized out so far. Probe TDAg and tripod enabling the execution of measurements on inductive casting machine INDUTHERM-VC 500D were designed for this technology especially. It was confirmed that one the method TDA can identify the crystallization process of the bronze in hot plaster moulds. The investigations of the superficial distribution of the concentration of elements in the microstructure of the studied grades of the bronze on X-ray microanalizer were conducted. It results that they be subject to in bronze CuSn10-C (B10) and the CuSn5Zn5Pb5-C (B555) of strong microsegregation from conducted investigations: Pb, Sn and Sb. The single separates of intermetallic phase \kappa was identified in the bronze B10 rich first of all in Zn, Sn, Sb and Fe, and two intermetallic phase, one rich were identified in the bronze B555 first of all in Zn, Sb, (Nor, Fe) and second rich in Sn, Sb, (Nor, Fe). The most homogeneous microstructure from the bronze CuAl10Fe5Ni5-C (BA1055) is characterizes among the studied grades of the bronze in the cast state.
2
Content available remote Selection of the temperature of casting the bronzes to plaster moulds
EN
The results of the investigations of the process of solidification of the bronze CuSn5Zn5Pb5-C (B555) and CuSn10-C (B10) in the hot plaster mould show in the work. For four temperatures of casting: 1200 o C, 1180 o C, 1160 o C and 1140 o C was conducted the investi-gation: the size of contraction cavity, the fulfillment of the mould cavity formative the casts of test slats about the thickness: 4 mm, 0,8 mm and 0,5 mm. It was conducted the investigation the processes sets in the arrangement the cast-mould and X-ray analysis phase XRD of compound coming into being in indirect layer created among mould and cast in the result of the thermal decomposition of the anhydrite. It results that the temperature 1140 o C is the optimum temperature of casting the bronze to hot plaster mould from carried out investigations. The minimum thickness of the wall of the cast from the bronze B555 is 0.5 mm, and from the bronze B10 0.8 mm. The realization of casts about thinner walls is made difficult because of giving off formed gases in the result of the thermal decomposition of the anhydrite. The products of the decomposition of the anhydrite react with elements steps in the chemical composition of studied bronzes, create in the arrangement the cast-mould the indirect layer folded from: sulphites, sulphides, oxides and clean metals (Pb) or their compounds, especially Sn and Sb.
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