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Biocidal Activity of Selected Preparations for Leather Protection

Falkiewicz-Dulik Michalina

Fibres & Textiles in Eastern Europe

2020

Vol. 28, no. 1 (139)

115--122

This research work involved the selection of biocides for the antimicrobial treatment of leathers. The scope of the research work covered microbiological tests of leather samples tanned utilising the same technology, with microbiological treatment made using 9 different preparations, as well as a test of leather without biostabilisation. Commercial biocides taken for inwestigation were as follows: NS 500 – an aqueous solution of nanosilver 500 ppm, ODH – tea tree oil, and OP – orange oil. Preparations prepared by diluting the purchased products were as follows: S27-22 – an aqueous solution containing silver chloride and titanium dioxide, SH 22-27 – an aqueous solution containing zinc pyrithione, ST 99-19 – an aqueous solution containing dimethyltetradecyl [3-(trimethoxysilyl)propyl]ammonium chloride, SU – an aqueous solution containing polyhexamethylene biguanide, and SGP – a saturated solution of aluminum potassium sulfate. Also a preparation was made by combining NS 500 M250 – 500 ppm nanosilver solution and a 250 ppm copper colloid. Evaluation of the effectiveness of biostabilisation of the leather samples and antimicrobial activity of the preparations used was carried out. Staphylococcus aureus and Escherichia coli bacteria and Candida albicans, Aspergillus brasiliensis and Trichophyton mentagrophytes fungi were used in the study. The assessment of microbial growth on samples was carried out according to Polish standards. Assessment of the resistance to bacteria and C. albicans yeast was made according to the PN-EN ISO 20645: 2006 standard – a method of diffusionon an agar plate. Assessment of the resistance to A. brasiliensis and T. mentagrophytes fungi was made according to the PN-EN ISO 14119: 2005 standard. Among the tested preparations to protect leathers against the effects of microorganisms, overall efficacy was obtained for SH 22-27, NS 500 M 250, SU and ODH.

Praca obejmowała dobór preparatów biobójczych do obróbki antymikrobowej skór. Zakres tematyczny obejmował badania mikrobiologiczne prób skór wyprawionych według tej samej technologii z obróbką mikrobiologiczną wykonaną przy użyciu 9 przygotowanych preparatów, a także test skóry bez biostabilizacji. Dokonano oceny skuteczności biostabilizacji skór i aktywności antymikrobowej użytych preparatów. Spośród testowanych preparatów do ochrony skóry przed działaniem drobnoustrojów najkorzystniejszą ocenę uzyskały: SH 22-27 zawierający pirytionian cynku, NS 500 M 250 zawierający nano cząsteczki srebra i miedzi, SU zawierający poliheksametylenobiguanidynę, ODH zawierający olejek melaleuca.

Impact Of Aerobic Biostabilisation And Biodrying Process Of Municipal Solid Waste On Minimisation Of Waste Deposited In Landfills

Dziedzic K., Łapczyńska-Kordon B., Malinowski M., Sikora J., Niemiec M.

Chemical and Process Engineering

2015

Vol. 36, nr 4

381--394

The article discusses an innovative system used for aerobic biostabilisation and biological drying of solid municipal waste. A mechanical–biological process (MBT) of municipal solid waste (MSW) treatment were carried out and monitored in 5 bioreactors. A two-stage biological treatment process has been used in the investigation. In the first step an undersize fraction was subjected to the biological stabilisation for a period of 14 days as a result of which there was a decrease of loss on ignition, but not sufficient to fulfill the requirements of MBT technology. In the second stage of a biological treatment has been applied 7-days intensive bio-drying of MSW using sustained high temperatures in bioreactor. The article presents the results of the chemical composition analysis of the undersize fraction and waste after biological drying, and also the results of temperature changes, pH ratio, loss on ignition, moisture content, combustible and volatile matter content, heat of combustion and calorific value of wastes. The mass balance of the MBT of MSW with using the innovative aeration system showed that only 14.5% of waste need to be landfilled, 61.5% could be used for thermal treatment, and nearly 19% being lost in the process as CO2 and H2O.