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EN
Vehicle emissions and performance fueled with waste cooking oil biodiesel is the main topic of this research. Biodiesel was produced through transesterification with physical and chemical characteristics comparable to diesel. B20 is a methyl ester of 20% blended with diesel. A diesel vehicle was modified and equipped with all measuring instruments needed to perform all experiments. The variable speed and load tests were conducted on the vehicle to measure the performance and emissions at different loads (0–30 kW) and different speeds (0–33 km/h). The vehicle speed was the maximum attained for each gear with a constant fuel flow rate without external fuel control at a steady state. At a vehicle speed of 33 km/h, the greatest increases in fuel consumption and exhaust gas temperature for biodiesel B20 were 17 and 6%, respectively, as related to pure diesel. At a vehicle speed of 33 km/h, B20 reduced the distance traveled, carbon monoxide and hydrocarbon concentrations compared to diesel by 22, 9 and 10%, respectively. At a vehicle speed of 33 km/h, the increases in nitrogen oxides and oxygen concentrations of B20 were 4 and 3% higher, respec-tively, than crude diesel over the whole tested load range. The biggest increases in distance, fuel consumption, and exhaust gas temperature for B20 over diesel were 13, 3, and 2%, respectively, at a vehicle load of 30 kW. The B20 blend decreased CO and hydrocarbon emissions related to diesel by 17 and 32%, respectively, at a vehicle load of 30 kW. The increases in nitrogen oxides and oxygen concentrations of B20 across the whole load range were 11 and 3% higher than pure diesel at a vehicle load of 30 kW, respectively. Biodiesel blend B20 is suggested for application in vehicles providing that the vehicle is moderately loaded.
PL
Głównym tematem badań podjętych w niniejszym artykule są emisje i osiągi pojazdów napędzanych biodieslem odpadowym z oleju spożywczego. Biodiesel powstał w procesie transestryfikacji o właściwościach fizycznych i chemicznych porównywalnych z olejem napędowym. B20 to 20% ester metylowy zmieszany z olejem napędowym. Zmodyfikowano pojazd z silnikiem diesla i wyposażono go we wszystkie przyrządy pomiarowe potrzebne do przeprowadzenia wszystkich eksperymentów. Przeprowadzono testy zmiennej prędkości i obciążenia pojazdu, aby zmierzyć jego osiągi i emisję przy różnych obciążeniach (0–30 kW) i różnych prędkościach (0–33 km/h). Prędkość pojazdu była maksymalną osiąganą na każdym biegu przy stałym natężeniu przepływu paliwa bez zewnętrznego sterowania paliwem w stanie ustalonym. Przy prędkości pojazdu wynoszącej 33 km/h największe wzrosty zużycia paliwa i temperatury spalin dla biodiesla B20 wyniosły odpowiednio 17 i 6% w porównaniu do czystego oleju napędowego. Przy prędkości pojazdu wynoszącej 33 km/h B20 zmniejszył przebyty dystans oraz stężenie tlenku węgla i węglowodorów w porównaniu do oleju napędowego odpowiednio o 22, 9 i 10%. Przy prędkości pojazdu wynoszącej 33 km/h przyrosty stężeń tlenków azotu i tlenu B20 były w całym badanym zakresie obciążeń odpowiednio o 4 i 3% większe niż w przypadku surowego oleju napędowego. Największy wzrost zasięgu, zużycia paliwa i temperatury spalin dla B20 w porównaniu z olejem napędowym wyniósł odpowiednio 13, 3 i 2% przy obciążeniu pojazdu 30 kW. Mieszanka B20 zmniejszyła emisję CO i węglowodorów związaną z olejem napędowym odpowiednio o 17 i 32% przy obciążeniu pojazdu 30 kW. Wzrosty stężeń tlenków azotu i tlenu B20 w całym zakresie obciążenia były odpowiednio o 11 i 3% wyższe niż w przypadku czystego oleju napędowego przy obciążeniu pojazdu 30 kW. Mieszankę biodiesla B20 zaleca się stosować w pojazdach pod warunkiem, że pojazd jest umiarkowanie obciążony.
EN
The experimental study was conducted to investigate the effect of using Cresson oil biodiesel on CI engine emissions and performance. This research aimed to examine how using innovative biodiesel blend formulations made from Cresson oil affected the performance and emissions of CI engines. The proportion of Cresson oil biodiesel added to conventional Iraqi diesel fuel into volume amounted to 10%, 20%, 40%, 60%, 80%, and 100%. The engine compression ratio was set to 18, and the fuel injection timing was set at 23º bTDC. The experiments show that this biodiesel reduces the thermal efficiency, heat release, delay time, and cylinder pressure of the engine while increasing the exhaust temperature (EGT) and brake-specific fuel consumption (BSFC). There has been an increase in emissions of nitrogen oxides (NOX) and carbon dioxide (CO2), in addition to a reduction in emissions of carbon monoxide (CO), soot, and unburned hydrocarbons (HC).
EN
Recently, there has been a growing interest in biodiesel due to its utilization of renewable resources, which is particularly significant given the increasing depletion of fossil fuel stocks. The utilization of Cresson weed in biodiesel fuel production is a pioneering application of botanical herbs within the biodiesel industry. This study compares the combustion characteristics of biodiesel fuel B10, B20, B40, B60, and D80B10M10 blends with petroleum diesel. This analysis examined the combustion process across various equivalence ratios in semi-industrial boilers. The study examined the combustion efficiency, flue gas emissions (CO, CO2, T exhaust, and HC), as well as flame length. The obtained findings show that adding more biodiesel fuel to diesel fuel increases its combustion efficiency above and beyond what is possible with regular diesel fuel at high energy levels. In addition, blends like B60 and other mixtures like D80B10M10 emit lower levels of pollutants, such as CO, than diesel as well as increase T exhaust and CO2, which indicates the completion of combustion.
EN
This study explored the ternary blends of biodiesel-diesel-n-butanol and biodiesel-diesel-n-octanol on common rail direct injec-tion (CRDI) diesel engines. The compositions of fuels, which varied from 0% to 100%, were altered by up to 5%. On the basis of their properties, these blends were chosen, with various concentrations of alcohol at 5% and 10%, 5% diesel, and the remainder being biodiesel. Two ternary fuel blends of waste cooking oil biodiesel (90–85%), diesel (5%), and butanol (5–10%), namely BD90D5B5 and BD85D5B10, and subsequently, another two ternary similar blends of waste cooking oil biodiesel (90–85%), diesel (5%), and octanol (5–10%), namely BD90D5O5 and BD85D5O10, were used to conduct the experiments. The experiments were done with varying injection pressure from 17° to 29° crank angle (CA) before top dead centre (bTDC). The optimum con-dition for the blends is achieved at 26°CA bTDC for 80% loading. So, the engine trials were conducted on 26°CA bTDC to attain the results. The BD90D5O10 blend achieved the lowest brake specific fuel consumption (BSFC) reading of 0.308 kg/kWh while operating at full load. The maximum brake thermal efficiency (BTE) was 31.46% for BD90D5B5. The maximum heat release rate (HRR) achieved with BD85D5O5 fuel blend was 58.54 J/°CA. The quantity of carbon monoxide that BD85D5B10 created was the lowest (25.86 g/kWh). BD85D5B10 had a minimal unburned hydrocarbon emission of 0.157 g/kWh while operating at full load. Oxides of nitrogen (NOx) were emitted in the maximum quantity by BD85D5O10, which was equal to 6.01 g/kWh. This study establishes the viability of blends of biodiesel and alcohol as an alternative for petro-diesel in the future to meet the growing global energy demand.
EN
Most countries in the world are facing two major challenges, one is the increase in the demand for energy consumption difficult to fulfill because of limited fossil fuel, and the second is the emission norms specified by many countries. Various methods are adopted to reduce emissions from engines but that leads to sacrificing the performance of CI engines. To eradicate this problem in the present study, the nanoparticles like (TiO2) are used with different particle sizes 1030 nm, 3050 nm and 5070 nm induced in B20 (20% biodiesel and 80% diesel) with the constant volume fraction of 100 ppm, and utilized in the diesel engine without any modifications. The results showed that the incorporation of TiO2 nanoparticles improves the combustion of hydrocarbons and reduces the emissions of CO, unburned hydrocarbon concentration, NOx and soot. Moreover, among three sizes of the nanoparticles, those with size 3050 nm showed interesting results with the reduction in brake-specific energy consumption, NOx, smoke and HC by 2.9%, 16.2%, 35% and 10%, respectively, compared to other blends used in the study, and hence the blend with the nanoparticle of size 3050 nm is expected to be a more promising fuel for commercial application in CI engines.
EN
Today, there is a growing shortage of commercial motor fuels in the world. This is due to the tendency to regulate the extraction of hydrocarbons, which are the main raw materials for their production; and, therefore, to reduce the import of oil, alternative types of fuel for diesel engines based on oils and animal fats are becoming widespread today. In this regard, intensive work is underway to convert internal combustion engines to biofuel-based ones both in countries with limited fuel and energy resources and in highly developed countries that have the opportunity to purchase liquid energy carriers. Biodiesel fuel (biodiesel, PME, RME, FAME, EMAG, etc.) is an environmentally friendly type of biofuel obtained from vegetable and animal fats and used to replace petroleum diesel fuel. According to the results of modelling, in the process of using RME B100 biodiesel fuel, we found a reduction in nitrogen dioxide emissions by 21.5% and a reduction in soot emissions by 34.5%. This will positively affect the environmental performance of the Sandvik LH514 loader, which is especially relevant in closed environments such as mines. So, according to the results of studies of the operation of the DD15 engine of the Sandvik LH514 loader on commercial and RME B100 biodiesel fuel, it was established that the use of biodiesel fuel leads to a deterioration of the mixture, due to which heat generation is reduced and, as a result, fuel consumption increases and engine power decreases, but the aspect of environmental indicators constitutes the significant improvement demonstrated by the present work.
7
Content available Zrównoważony rozwój metod otrzymywania biodiesla
EN
The increase in urbanization and the growing demand for petroleum products, fuels and energy correlates with the depletion of resources of non-renewable energy sources such as crude oil, hard coal, and natural gas. Due to the high emissions of greenhouse gases, i.e., carbon oxides(COx), nitrogen oxides (NOx) and sulfur oxides (SOx), the use of fossil fuels causes drastic climate changes [1]. Therefore, new, "green",sustainable, and renewable energy sources, e.g., biofuels, are currently being sought. Such interests of scientists are in line with people's most urgent needs due to the rapidly depleting oil resources, the increase in fuel prices and the degradation of the natural environment. Biodiesel is one of the most widely used biofuels due to its more positive impact on the environment (compared to diesel fuel), and technical and strategic advantages. Therefore, in this review, we would like to draw attention to the sustainable development of biodiesel synthesis methods, the progression of advanced technologies supporting this process, and the various types of reactors for biodiesel production (for example, a membrane or microwave reactor) will also be discussed [1].
EN
As environmental requirements become more stringent and the planet becomes more polluted, the replacement of conventional diesel is attracting more interest. For alternative fuels, such as biodiesel and natural gas, to be used, their effects must be examined not only in terms of the engine’s environmental indicators but also in terms of engine vibrations and sound pressure. This study examined the influence of dual fuel – biodiesel and natural gas – on vibrations and sound pressure of a compression-ignition (CI) engine. Conventional diesel or hydrotreated vegetable oil biodiesel was used as a pilot fuel for gas ignition. The gaseous fuel was natural gas, which was injected into the intake manifold with different energy shares of the gaseous fuel (40%, 60% and 80%). Tests were performed at a constant engine crankshaft speed and a fixed start of pilot fuel injection of 6° BTDC while the fuel composition and engine load were changed. This experiment revealed correlations between gas energy share (GES) in liquid fuel and ecological and energy indicators of a CI engine.
EN
Biodiesel is regarded as a clean fuel alternative to fossil diesel fuel for fewer pollutant emissions of internal combustion engines. The biodiesel type can be made from waste frying oil, thus it has to be done right. Waste vegetable oil can be provided for free or at a low cost by restaurants and food processors that often use frying oils. Animal fat is also available for free or for a nominal fee from grocery stores, restaurants, and butchers who use lots of fats in their cooking. The methyl ester of oleic acid methyl ester (OAME) biodiesel was produced from used vegetable oil using the transesterification process in order to compare the performance of the 67 kW KUBOTA tractor diesel engine when utilizing OAME and fossil diesel. OAME biofuel was used without being mixed. The engine’s reliability metrics and important indicators, including the brake torque, indicated power, brake-specific fuel consumption (BSFC) and burn duration, were identified. Optimal implementation was met by fossil diesel and the tested characteristics were very close. The OAME biofuel performs better in terms of volumetric efficiency and duration of combustion than the conventional diesel. The decision to choose a specific biofuel that is produced from a particular source so largely hinges on its availability and economic feasibility wherever it is used.
EN
The olive mill wastewater, effluents from the trituration of olives, are treated in most Mediterranean countries by natural evaporation. However, this method of treatment is a source of air and soil pollution by the generation of solid waste, called olive mill waste cake. This work focused on extracting of vegetable oil from this by-product for biodiesel production by transesterification. The extraction took place with a Soxhlet extractor, using hexane as solvent. The vegetable oil and biodiesel were characterized by measuring the physicochemical parameters that identify them according to AFNOR standards. The extraction results show that the oil yield is 21.28%. The oil obtained is characterized by density, water and ash content, acidity, saponification, peroxide and ester. The yield of the oil esterification reaction is 86.41% or about 185 Kg of biodiesel/ton of olive mill waste cake, and in terms of energy 2783.7 MJ or 2 GW.t-1. The biodiesel produced is comparable to petroleum diesel according to EN 14214, 2013.
EN
Restaurants and food processors that frequently utilize frying oils can provide waste vegetable oil for free or for a small price. To compare the use of OAME to fossil diesel on the performance of the 67 kW Kubota tractor diesel engine, the methyl ester of oleic acid methyl ester (OAME) biodiesel was created from used vegetable oil using the transesterification process. The OAME gasoline was used straight up. The engine’s performance parameters and key indications, such as the indicated torque, brake torque, indicated power, fuel consumption of the braking force brake (BSFC), and exhaust gas emissions, were determined. The choice of a certain biofuel made from a specific source is primarily based on its economic viability and availability where it is utilized.
EN
The objective of this study is to compare the performance of diesel engines, fuelled with biofuel blends extracted from corn, sunflower, and palm oils, against pure diesel. The experiments were performed using Lister LVI, single-cylinder, direct injection, four-stroke engines, with a compression ratio of 17:1. The following parameters were analysed: brake torque, brake mean effective pressure (BMEP), brake specific fuel consumption (BSFC), brake thermal efficiency (BTE), and exhaust gas temperature (EGT). The findings indicate that the characteristics of biodiesels are close to diesel fuel. Therefore, biodiesel becomes a viable alternative to diesel fuel without any modifications. Pure diesel has higher brake thermal efficiency and lower BSFC than all the biodiesel blends tested in this study. In addition, the engine consumes less fuel for biodiesel blends than pure diesel. High exhaust temperatures are conducive to nitrogen oxides (NOx) generation; hence, this study reveals that the exhaust temperature is reduced when utilizing biodiesel compared to pure diesel. According to several tests, palm biodiesel provides greater torque and BMEP than the rest of the biodiesel blends, and pure diesel due to emitting less NOx. Therefore, it stands to reason that it would be utilized in a diesel engine.
13
Content available Katalizatory wykorzystywane w syntezie biodiesla
EN
Rising prices of electricity, conventional fuels and heating require decisive steps in the further development of technologies based on renewable energy sources. These include geothermal- ; hydrothermal- ; aerothermal- ; and solar energy. Due to the fact that the petrochemical industry is one of the fastest growing branches of the economy, we would like to expand on the topic related to biofuels. Biodiesel is an alternative fuel similar to conventional diesel. It is usually made from animal fat, vegetable oil and waste cooking oil. Its biodegradability, nontoxicity and lack of sulfur and aroma content make it superior to conventional gasoline and diesel. During fuel consumption, it emits fewer air pollutants and greenhouse gases other than nitrogen oxides. In this literature review, we will discuss the latest trends in the world related to catalysts used in biodiesel synthesis.
EN
Biodiesel is currently preferred for consumption and has been widely used as a substitute for diesel. This study aimed to determine the effect of various methanol-to-oil ratios in the esterification process and also the effect of hydrotalcite catalyst weight on the transesterification product. The catalyst was characterized with SEM, XRD, FTIR, and TG-DTG-DTA. The esterification process was operated at various oil-to-methanol ratios, i.e., 1:12–1:36 and the transesterification was performed using several catalyst weights, 0.5%–2.5%. The results showed that the optimum conditions of esterification were at the 1:30 molar ratio of oil-to-methanol, which decreased the amount of acid number by 95.75%, while the optimum condition of transesterification was at 1.5% catalyst weight. The characteristics of biodiesel using 0.5–2% hydrotalcite catalyst (acid number, total glycerol, free glycerol, ester levels, viscosity, density, oxidation stability) have met the Indonesian biodiesel standard of SNI-04-7182-2012.
EN
Biodiesel is one type of renewable alternative energy that has great potential to be developed. Biodiesel is a fuel consisting of a mixture of mono-alkyl esters of long-chain fatty acids made from renewable sources, such as vegetable oils or animal fats, one of which is crude palm oil (CPO). Crude palm oil contains free fatty acids in high levels, so treatment is needed to reduce free fatty acids by a reaction known as the esterification reaction. Then, the transesterification process is carried out to produce biodiesel (methyl ester). The purpose of this study was to analyze the effect of catalyst mass, a mole ratio of CPO to moles of methanol and the effect of adding THF co-solvent to biodiesel purity. The catalyst used is a heterogeneous catalyst from kapok fruit peel waste. Kapok fruit rind was calcined at 700°C for 8 hours. The independent variable varied the mole ratio of oil to methanol in a 1:4 ratio; 1:6; 1:8; and 1:10 with a catalyst weight variation of 3 and 4%. Meanwhile, for the addition of co-solvent, variations of THF: methanol v/v 1:1 and 2:1, were carried out. The biodiesel properties such as density, viscosity, water content and acid number, were evaluated and compared with the Indonesian National Standard. The results showed that the transesterification reaction with the addition of co-solvent resulted in a higher methyl ester content than that without the addition of co-solvent. The highest yield of methyl ester without the addition of co-solvent was 79.16%, while the yield of the methyl ester with the addition of THF co-solvent with a ratio of 1:1 and 2:1 v/v to methanol was 90.09 and 94.09%, respectively. The highest methyl ester content (94.09%) was achieved by the addition of THF: methanol = 2:1, CPO: methanol molar ratio = 1:6 and 4 wt% catalyst weight. The results obtained in this study indicate that a green catalyst made from kapok skin can be used to produce biodiesel and also the addition of co-solvent can increase the yield of methyl esters, so that high purity is obtained.
EN
The internal combustion engine plays a vital role in transportation, industry, and shipping. However, diesel as one of the main fuels for internal combustion engines, caused many environmental and human health problems. In order to solve the problems, more researchers have been committed to the research of alternative fuels. Biodiesel is a renewable, sustainable alternative fuel, and its characteristics are similar to traditional diesel. It can be mixed with pure diesel. It has been found that a mix with pure diesel in a certain ratio can effectively reduce the negative effects caused by its characteristics, improve the combustion performance, and reduce the NOx and PM emissions. This article mainly reviews the effects of the mixture of biodiesel and diesel on engine combustion characteristics and exhaust emissions, including three parts: part (1) summarizes and analyzes the biodiesel’s production and characteristics, part (2) analyzes the engine’s performance under different working conditions, and part (3) studies and analyzes the exhaust emission under different working conditions.
PL
Z ponad 51 000 statków handlowych i kilku tysięcy okrętów marynarki pływających po otwartych morzach i oceanach, zanieczyszczenie mórz stało się znaczącym czynnikiem nie tylko globalnej zmiany klimatu, ale także szybkiego zaniku życia morskiego i niszczenia ich cennych ekosystemów. Wraz z szybkim postępem technologicznym w inżynierii, produkcji, transporcie itp. wzrosła potrzeba szybszych, wydajnych i czystszych technik.
EN
The paper presents the experimental test results reflecting the comparative changes in the performance efficiency and emissions of the exhaust of a naturally aspirated, four-stroke, single-cylinder, air-cooled diesel engine due to its transition from neat rapeseed oil biodiesel to fuel blends prepared by mixing in various proportion (by volume) rapeseed methyl ester (B) and butanol (Bu). The lubricity properties of biodiesel-n-butanol fuel blends were studied using HFRR method. In contrast to previous works, the undertaken investigation is performed with a totally renewable, binary liquid biofuel blends. The purpose of the research is to reduce simultaneously the production of NOx emissions and the exhaust smoke with respect to neat biodiesel due to potentially improved homogeneity of combustible mixture and particulate matter emissions benefits suggested by the higher oxygen content (21.62 wt%) and the relatively lower carbon-to-hydrogen ratio (4.8) of the normal n-butanol. The tests revealed that the brake specific fuel consumption for the binary biodiesel-n-butanol fuel blends is always higher than that neat biodiesel produces under the same loading conditions. Maximum nitrogen oxide (NOx) emissions were obtained with the engine running on neat biodiesel (2290 ppm). At full (100%) load conditions, the lowest NOx emission was obtained with the engine running on a biofuel BBu20 blend. The lowest level of carbon monoxide emissions (CO) was observed, when engine running with the most butanol-oxygenated biofuel blend BBu20.The highest smoke opacity of the exhaust was obtained when the engine was fuelled with neat biodiesel and at full load.
EN
The purpose of this study is to experimentally investigate the performance of compression ignition engine using a biodiesel extracted from waste cooking oils (WCO), such as, falafel frying palm oil, chicken frying soybean oil, and fresh oils, such as soybean and olive oils. After producing biodiesel from WCO and fresh oils, the mixtures were blended with pure diesel in two percentages as follows: B20 (20% biodiesel from each type, 80% pure diesel) and B10 (10% biodiesel from each type, 90% pure diesel). The biodiesel blends were used as an alternative fuel for diesel engine. The ignition performance of the fuel blends was compared with that of pure diesel B00 (0% biodiesel, 100%pure diesel). To analyze the effect of biodiesel on engine performance, the engine was operated at variable load from 0 to 6 kW and constant speed at 2000 RPM. For engine performance, brake power, brake specific fuel consumption and brake thermal efficiency were analyzed. The results showed that pure diesel produces higher brake force (BP) than all biodiesel blends. The highest value for brake specific fuel consumption (BSFC) at variable load is for B20-F (20% biodiesel from falafel frying oil, 80% pure diesel) is equal to 0.243426 gm/kW.s. The highest value for brake thermal efficiency (BTE) is for B10-S (10% biodiesel from soybeans oil, 90% pure diesel) is equal to 27.6%.
EN
In the present work, biofuels produced from different raw fatty materials have been proposed as a dominant fuel component in biodiesel-diesel fuel blends. Biofuels were produced from pork lard and rapeseed oil by alkali transesterification using methyl alcohol. Blends of biofuels in volumetric proportions of 60 and 80% of the biocomponent and the remaining part of the conventional fuel were used in a compression ignition engine designed for medium-duty vehicles. The experiments were conducted at two engine rotational speeds (1500 and 3000 rpm, respectively) and a set of load conditions (50, 100, and 200 Nm, respectively). The tests focused on engine efficiency parameters (brake-specific fuel consumption and brake fuel conversion efficiency) as well as exhaust gas emissions (hydrocarbons, carbon monoxide, and carbon dioxide were determined). The obtained results indicate that blends containing biocomponents produced from pork lard were characterized by superior fuel consumption and efficiency results, compared to blends containing biocomponents produced from rapeseed oil. In terms of exhaust emissions, biocomponents produced from pork lard were also characterized by lower emission of all of the examined components compared to rapeseed methyl ester-diesel blends. This study proposes that fuel components obtained from custom (animal) raw-fatty material can be an effective substitute for commonly used rapeseed oil methyl esters.
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