Wyniki wyszukiwania - BazTech

Ograniczanie wyników

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Wyszukiwano:
w słowach kluczowych: binary liquid mixture

Sortuj według:

Ogranicz wyniki do:

Comparative Study of Experimental and Theoretical Ultrasonic Velocities in Binary Mixtures of Cyclohexanone with Aliphatic Esters at Different Temperatures

Divakar P. P., Samatha K.

International Letters of Chemistry, Physics and Astronomy

2015

Vol. 42

13--24

Ultrasonic velocity evaluated by various theoretical relations viz., Nomoto, Free Length Theory (FLT), Van deal and Vangeel ideal mixing relation (IMR), Impedance Dependence Relation (IDR), and Junjie in three binary liquid mixtures of cyclohexanone as a common component with aliphatic esters (isopropyl acetate, isobutyl acetate and isoamyl acetate) at 303, 308, 313 and 318K over the entire composition range. An attempt has been made to compare the merits of the relations and the relative applicability of these theories to the present systems have been checked and discussed. The results are explained in terms of intermolecular interactions occurring in these binary systems. The deviation in the variation of U2exp / U2 imx from unity has also been evaluated for explaining the non-ideality in the mixtures.

Critical fluctuations of a confined binary mixture

Zubaszewska M., Gendiar A., Masłowski T.

Journal of Applied Mathematics and Computational Mechanics

2014

Vol. 13, nr 4

177-182

Exploiting the mapping between a binary mixture and the Ising model we have analyzed the critical fluctuations by means of the density-matrix renormalization group technique. The calculations have been carried out for a two-dimensional Ising strip subject to equally strong surface fields. It was found that the critical Casimir force has significantly different behavior on opposite sides of the capillary condensation line, especially below the critical temperature. It can be concluded that in real binary mixtures the most attractive force appears at temperatures near Tc and at reservoir compositions slightly away from the critical composition.