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2 Opto-Electronics Review

2 2009

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Molecular theoretic study of Freedericksz transition : symmetry breaking of oblique axial order

Kio M., Torikai M., Yamashita M.

Opto-Electronics Review

2009

Vol. 17, No. 1

8-15

Freedericksz transition, which is usually analyzed by an elastic theory, is studied on the basis of statistical mechanical ground, where nematics with positive dielectric anisotropy in homogeneous anchoring cell is exposed to an electric field in the direction of wall normal. In low temperature region, an oblique axial symmetry breaking occurs, which is nothing but the Freedericksz transition. In high temperature and high field region, biaxial nematic phase with principal axis parallel to the field direction at interior area of the system is proved to appear. A phase diagram on the field versus temperature plane is obtained and compared with the one at a bulk with common biaxial symmetry, where both of electric and magnetic fields are applied in directions perpendicular to each other. In the latter, no symmetry breaking occurs, in contrast with the former case above-mentioned, and the reason why this difference occurs is elucidated.

Effects of fields and anchoring on biaxial nematic ordering

Yasen M., Torikai M., Yamashita M.

Opto-Electronics Review

2009

Vol. 17, No. 2

89-94

Symmetry of a nematic liquid crystal phase is broken by an anchoring wall and also by an external field. Nematic system sandwiched between biaxial anchoring walls is introduced as a correspondent to a bulk nematic system exposed to a couple of fields, an electric field and a magnetic one in directions perpendicular to each other, and thermal behaviours of the system are studied. The crossover between a homeotropic structure and homogeneous one occurs, similarly to the bulk system in the fields, in which the anchoring condition of coexistence is shown to have the same expression as the one at the bulk. As to a characteristic phenomenon at the sandwiched system, it is proved that an appearance of a biaxial nematic order suppresses a uniaxial nematic order. A surface transition, i.e., a wetting phenomenon is shown to occur also in the biaxial nematics, even though the uniaxial order is suppressed therein.