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1 2008

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Metallo-Supramolecular Assemblies Incorporating 1,3- and 1,4-Aryl Linked Bis-beta-Diketones - Some Recent Studies

Clegg J. K., Jolliffe K. A., Lindoy L. F., Meehan G. V.

Polish Journal of Chemistry

2008

Vol. 82, nr 6

1131-1144

A review of recent work in the authors laboratories in volving the interaction of 1,3- and 1,4-aryl linked bis-beta-diketone derivatives with divalent and trivalent metal ions is presented. In some in stances, bifunctional bridging ligands have been employed to extend the resulting structures from two to three dimensions. Examples of metallosupra molecular dinuclear 'platforms', tetranuclear cofacial dimers, dinuclear helicates, trinuclear triangles, stepped metallo-polymers, a prismatic columnar polymer and large cavity-containing, tetranuclear tetrahedra are all discussed.