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1 2009

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Bimetallic Ag(I)-Cu(II) Assembly with Extended Oxamido-Bridged: Synthesis, Crystal Structure and Magnetism

Ma S. L., Ren S., Zhang H. Y.

Polish Journal of Chemistry

2009

Vol. 83, nr 1

39-46

A new bimetallic compound Cu2(oxae)(H2O)2Ag2(CN)4 (1) (oxae = N,Nc- bis(2- amino - ethyl)oxamidodianion) was isolated and structurally characterized. Compound 1 crystallizes in the monoclinic system, with space group P21/c and unit cell constants a = 14.033(18), b = 7.165(9), c = 9.378(12) Capital a, beta = 103.890(14) graduate and Z = 2. The com plex 1 consists of the oxamido-bridged binuclear copper(II) unit and two linear cyanoargentate anions acting as monochelate ligands. The coordinated environment of the Cu atom is a square prism. The complex 1 is self-assembled into three-dimensional (3D) network via hydrogen bonds. The magnetic properties of 1 have been studied as well.