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1 2009

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Volumetric, Viscometric, and Refractive Index Studies of Some alfa-Amino Acids in Aqueous Tartrazine at Different Temperatures

Ali A., Patel R., Shahjahan, Tasneem S.

Polish Journal of Chemistry

2009

Vol. 83, nr 7

1353-1363

The densities (r), viscosities (h), and refractive indices (nD) of (0.10, 0.15, 0.20, 0.25, and 0.30) m glycine, L-alanine, and L-valine were measured in 0.01 m aqueous tartrazine at 288.15, 293.15, 298.15, 303.15, 308.15, and 313.15 K. The measured data were utilized to evaluate various use ful parame ters, viz., apparent molar volume, (fi ni ), partial molar volume, (fi ni o), partial molar isobaric expansibility, (fi i E o ), transfer volume (fi ni o (tr)), A and B – coefficients of viscosity, free energy of activation of viscous flow per mole of solvent (Delta mi 1 o*) and solute (Delta mi 2o*) and molar refractivity (RD). The linear varia ion of fi ni o with the number of carbon atoms (nC) present in the alkyl chain of amino acids was also considered for the evaluation of the contribution of zwitterionic end groups (NH3 + , COO–) and methylene groups to fi ni o. The results were used to discussion–ion, ion–nonpolar and nonpolar–nonpolar interactions and the presence of structural hydration in the present systems.