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2 Bulletin of the Polish Academy of Sciences. Technical Sciences

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Active glasses as the luminescent sources of radiation for sensor applications

Żmojda J., Dorosz D., Kochanowicz M., Dorosz J.

Bulletin of the Polish Academy of Sciences. Technical Sciences

2014

Vol. 62, nr 2

393--397

The article presents physicochemical, thermal and spectroscopic properties of two different glass systems: TeO2-GeO2-PbO-PbF2- BaO-Nb2O5-LaF3 and SiO2-Al2O3-Sb2O3, co-doped with Yb3+/Tm3+ ions. Blue upconversion luminescence at a wavelength of 478 nm corresponding to the thulium 1G4 ⇥3H6 transition was observed under 976 nm pump radiation in both of the co-doped glasses. This indicated the existence of efficient Yb3+ ⇥ Tm3+ energy transfer via three-photon absorption mechanism. Thermal and optical results substantiate the claim for practical applicability of the manufactured glasses in design of optical fiber sources.

2.1 žm emission of Tm3+/Ho3+ - doped antimony-silicate glasses for active optical fibre

Żmojda J., Dorosz D., Dorosz J.

Bulletin of the Polish Academy of Sciences. Technical Sciences

2011

Vol. 59, nr 4

381-387

Tm3+/Ho3+ – doped antimony-silicate optical fibre with 2.1 ěm emission has been presented. Luminescence corresponding to 5I7 --> 5I8 transition in holmium was obtained by energy transfer between Tm3+ and Ho3+ ions. The analysis of the luminescence mechanism showed a significant influence of the glass composition (low phonon content) on the emission intensity. Optimization of the active elements content, presented in the paper, allowed to indicate that a strong emission intensity at 2 ěm in the fabricated glasses was obtained for the molar composition of 1% Tm2O3 : 0.75% Ho2O3. According to the F¨orster-Dexter theory, the efficiency of energy transfer of the 3F4 (Tm3+) --> 5I7 (Ho3+) transition was calculated. Moreover, it was found that the full width at half maximum (FWHM) of luminescence in the range of 1.6 – 2.2 ěm strongly depends on the Tm3+/Ho3+ ratio. The optimization of Tm3+/Ho3+ transfer in antimony-silicate glasses allowed to fabricate optical fibre with narrowing and red-shifting of emission at 2.1 ěm.