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EN
Purpose: Presentation of different anodizing methods used for formation of thin, thick, gel like covered and nanostructural titania and alloy component oxides. Evaluation of their properties for various biomedical applications in implantology and biosensing. Design/methodology/approach: Samples of titanium and its alloys were anodized in phosphoric acid solutions at different concentrations (0.5 ~ 4 M) with or without additions according to appropriate polarization regimes. Anodized samples were characterized by SED+EDS, electrochemical and impedance (EIS) tests and biocompability examination. Titanium and its alloys (Ti6Al4V and Ti6Al7Nb) samples were also used to form the nanostructural layer (nanotubes) by anodizing. The latter was used as a platform for glucose biosensing. Findings: Anodizing of titanium materials in phosphoric acid solutions allowed to obtain surface layers of various morphology and topography. They differ in porosity, thickness and chemical composition and according to their specific properties can be used in various biomedical applications. The development of gel-like layer and formation of nanotube layer was observed while anodizing in higher concentration of electrolyte or anodizing in the presence of fluorides. Both surface layers are much more bioactive than anodic barrier oxide layers on titanium. The primary tests to use nanostructured layer as platform for the third generation biosensors were promising. Practical implications: Use of medical implants covered with porous and nanostructural anodic layers tailored to particular biomedical purposes enables new practical applications in implantology and biosensing. Originality/value: Phosphate gel-like layer over surface oxide layer on titanium materials and nanostructural surface layer rich in both: phosphates and fluorides, are highly bioactive, which is the desirable property of implant materials.
PL
W pracy charakteryzowano elektrochemiczne własności warstw tlenkowych na implantowym stopie tytanu Ti6A14V ELI powstałych w procesach: polerowania oraz anodowania. Oceniano także wpływ odkształceń plastycznych wywołanych gięciem na zachowanie in vitro obu warstw. Badania prowadzono po 1 i 37 dniach przechowywania w roztworze Ringera. Do oceny zachowania warstw tlenkowych zastosowano pomiary potencjałów korozyjnych, interpretację krzywych polaryzacyjnych oraz elektrochemiczną spektroskopię impedancyjną. Rezultaty badań wykazały różnice w zachowaniach naturalnej oraz anodowej warstwy-tlenkowej przy dążeniu do stanu "równowagi", odpowiadającego warunkom badań in vitro.
EN
In this investigation, the behavior of oxide layers titanium alloy Ti6A14V arised during: anodizing and polishing was characterized in bending test. Influence of plastic deformations on both layers was estimated in vitro. Measurements were performed after 1 and 37 days immersion in Ringer's solution. The behavior of layers was characterized by electrochemical testing (anodizing polarization, EIS and corrosion potential). A measurement of corrosion potential, electrochemical impedance, spectroscopy and interpretation of polarization curves was used to estimate oxide layers. Results of investigation show differences between natural and anodic oxide layers. Bending gives positive influence on bioactivity.
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