The synthesis of N-arylamino(ferrocenyl)methylphosphinic acids by the action of hypo - phosphorous acid on anazomethine bond of ferrocenyl N-aryl Schiff bases is described. Ferrocenyl aminophosphinic acids obtained in this way have been converted into their cholesteryl esters by their reaction with cholesterol in the presence of DCC.
Practical general procedures of N-acylation of 1-aminoalkanephosphonic acids, including N-acetylation, N-benzoylation and N-pivaloylation of the representative aminophosphonic acids are described. Physico-chemical properties of synthesized derivatives are presented. Dissociation equilibria, determined for some representative 1-(N-acylamino) alkanephosphonic acids, are listed.
Imidazole aminophosphonic and imidazole aminophosphinic acids were synthesized by treatment of imidazole aldimines with silylated phosphorus acid esters. The aldimines were obtained from corresponding imidazolecarboxaldehydes and primary amines.
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