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2 Polish Journal of Chemistry

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Thiophosphates and Selenophoosphjates as Tools in the Construction of Carbon-Carbon Double Bond

Skowrońska A., Dybowski P., Koprowski M., Krawczyk E., Maciągiewicz I.

Polish Journal of Chemistry

2001

Vol. 75, nr 8

1121-1135

Efficient new methodology of regio- and stereoselective synthesis of a variety of functionalized mono- and polycyclic compounds based on thio- and selenophosphates is reported. The representative examples of these compounds are: vinyl thiiranes, conjugated dienes, cycloadducts, _,_-unsaturated carbonyl compounds, allylic alcohols, _-hydroxy ketones and aromatic compounds.

Reaction of allylic alcohols with aliphatic alcohols in the presence of cerium(III) chloride. Part II

Uzarewicz A., Dresler R., Ścianowski J.

Polish Journal of Chemistry

1998

Vol. 72, nr 4

710-718

The reaction of selected allylic alcohols with methanol, ethanol, n-propanol, isopropanol and tert-butanol in the presence of catalytic amounts of cerium(III) chloride are described. Allylic alkyl ethers, bis-allylic ethers and 1,3-dienes were obtained depending on the structure of the reacting alcohols .