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1 Materials Science Poland

1 2004

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Spectral studies of new organic conductors based on TTF derivatives with polymeric isocyanuric acid anions

Barszcz B., Łapiński A., Graja A., Flakina A. M., Lyubovskaya R. N.

Materials Science Poland

2004

Vol. 22, No. 4

339--346

Spectral investigations of new organic conductors (BEDO-TTF)2(C3H2N3O3) and (DB-TTF) (C3H2N3O3) were performed. Optical absorption spectra in the range of 400-40 000 cm-1 of the powdered salts dispersed in KBr pellets were recorded and analysed. The spectra of (BEDO-TTF)2(C3H2N3O3) are characteristic of organic metals and show small anisotropy, which is typical of quasi-two-dimensional materials. On the other hand, the spectra of (DB-TTF)(C3H2N3O3) are typical of semiconducting materials. The (BEDO -TTF)2(C3H2N3O3) salt undergoes a phase transition at about 120 K. The polarized reflectance spectra of single crystals of (BEDO-TTF)2(C3H2N3O3) were recorded in the range of 600-7000 cm-1, down to 4 K. The frequency dependences of reflectivity were fitted with a Drude model and the transport parameters were evaluated and investigated vs. temperature. An assignment of some vibrational bands in the IR spectra was proposed.