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Experimental Study of Produced Water Treatment Using Activated Carbon with Aluminum Oxide Nanoparticles, Nanofiltration and Reverse Osmosis Membranes

Hussein Mudhaffar Yacoub, Al-Naemi Amer Naji Ahmed, AlJaberi Forat Yasir

Journal of Ecological Engineering

2023

Vol. 24, nr 5

78--87

This work inspected the produced water discharged from the Amara oil field in (Misan-Iraq) to improve the quality of water before reuse and reinjection or disposal. The process of treatment included a pretreatment step using activated carbon and post-treatment using flat polymeric nanofiltration membrane (NF) (1.0 nm) and reverse osmosis membrane (RO) (0.3 nm), respectively. Therefore, activated carbon without aluminum oxide (Al2O3) nanoparticles and with (Al2O3) nanoparticles (20 nm) was used to examine the removal efficiency of the total organic compound (TOC). The height of the fixed bed of activated carbon and its diameter were 35 cm and 2.5 cm, respectively. The volumetric flow rates of the produced water flowing through the activated carbon column were taken as (25, 20, 15, 10 and 5)×10-4 m3/h respectively, at transmembrane pressure (TMP) of 1.0 bar, pH equals 6, and the temperature of 25 °C. The TOC removal efficiencies attained using activated carbon without Al2O3 nanoparticles were (52, 64, 77, 83 and 87%), respectively, and (65, 72.7, 83.4, 92.5 and 95.2%) with the use of Al2O3 nanoparticles, respectively. Produced water effluent from the activated carbon column was treated by flat NF and RO membranes to reduce the total dissolved solids (TDS). The cross-flow rates through NF and RO membranes were 0.1 and 0.25 m3/h, TMP (1–12 bar) and 60 bar, respectively. The removal efficiency of TDS was enhanced up to 40% and 99.67%, respectively. In addition, the TOC removal efficiency was 100% in the effluent of the RO membrane.

Treatment of evaporative water from brewer’s yeast concentration by Fenton and Fenton-like processes

Michel M. M., Reczek L., Siwiec T., Rudnicki P.

Archives of Environmental Protection

2018

Vol. 44, no. 3

11--18

Evaporative water from yeast slurry concentration is acidic, low mineralized and contains large amounts of dissolved organic contaminants. The treatment of evaporative water from yeast slurry concentration by Fenton (Fe(II)/H2O2) and Fenton-like (Fe(III)/H2O2) reactions has been studied. The processes in terms of system variables have been compared: catalyst and oxidant doses, initial pH, temperature of reaction, and the reaction kinetic. For determination of mineralization efficiency the total organic carbon (TOC) in water before and after reactions was measured. The Fenton reaction was more efficient for mineralization of organic compounds: the highest efficiency of TOC removal was 45–50%, while for the Fenton-like it was 20–30%. The pH adjustment of evaporative water in the range of 2–5 did not change the efficiency of treatment. Temperature of 30°C was the most favorable for both reactions. The Lumped Kinetic Model fitted very well the experimental results. The reaction rate analysis indicated that the rate of direct mineralization of organic compounds is similar to the rate of its oxidation to organic intermediates, its selectivity factor was more favorable to the Fenton reaction. The strong correlation between chemical oxygen demand (COD) and TOC in evaporative water after the Fenton and Fenton-like reactions has been determined, providing a simple tool for calculating COD on the basis of values of TOC measurement.

Woda wyparna z zatężania gęstwy drożdżowej jest kwaśna, nisko zmineralizowana i zawiera dużą ilość rozpuszczonych związków organicznych. W pracy badano oczyszczanie wody wyparnej w reakcji Fentona (Fe(II)/H2O2) i pokrewnej (Fe(III)/H2O2). Porównywano procesy przy następujących zmiennych: dawki katalizatorów i utleniacza, pH początkowe, temperatura i kinetyka reakcji. Efektywność oceniano poprzez pomiar ogólnego węgla organicznego przed i po reakcji. Związki organiczne były bardziej skutecznie mineralizowane w reakcji Fentona: najwyższa efektywność usuwania OWO wynosiła 45–50%, a w reakcji pokrewnej jedynie 20–30%. Korekta odczynu wody wyparnej w zakresie 2–5 pH nie wpłynęła na efektywność oczyszczania. Temperatura 30°C była najbardziej korzystna dla obydwu reakcji. Model kinetyczny o parametrach skupionych bardzo dobrze opisywał wyniki badań eksperymentalnych. Analiza szybkości reakcji wykazała, że jest ona zbliżona w przypadku mineralizacji organicznych składników oraz utleniania do produktów pośrednich, a współczynnik selektywności reakcji był korzystniejszy dla procesu Fentona. Określono silną korelację pomiędzy parametrami ChZT i OWO w wodzie po reakcji Fentona i pokrewnej, co może być przydatnym do obliczania ChZT na podstawie pomiaru OWO.