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Experimental analysis of flyash based, ion exchanged zeolite as catalyst for SI engine exhaust emission control

Karthikeya D., Saravanan C. G.

Journal of KONES

2013

Vol. 20, No. 3

229--235

Lean Burn gasoline engines are receiving increasing application because of their potential of improved fuel economy. The conventional three-way converter used in gasoline engines controls effectively the levels of CO and HC, but it displays poor conversion in harmful NOx emission. This study has investigated the use of different materials with metal additives as support for effective NOx control in gasoline engines. In this work, flyash, which is relatively abundant and inexpensive, has been used as a replacement for expensive materials. Development of Catalysts from waste materials is an effective means to enhance the value of the waste. In the present work, X-Zeolite was synthesized from Coal Fly ash. 13-X zeolite was purchased from market. By the process of exchanging Na+ ions present in these zeolites with copper, Silver and Iron metal ions separately, six catalysts were prepared. Investigations were carried out on the 3 cylinder, 4-stroke, water cooled Maruthi Omni Gasoline Engine with a displacement volume of 796 cc and coupled with eddy current dynamometer. The packed catalyst bed was housed in a 100 mm diameter cylindrical pipe and is connected near to the exhaust manifold. AVL Di-gas analyser is used to measure the NOx, CO, HC, CO2, O2 emissions. Experiments were conducted at various loads from no load to maximum load without catalytic converter and then using the Ag-X, Ag-13X, Fe-X , Fe-13X, Ni -X and Ni -13X zeolite catalytic converters. The result reveals that in house made Ag-X , Fe-X and Ni -X Catalysts reduce emission at all levels of load conditions. Ag-X catalyst gives better conversion than Fe-X catalyst and Ni-X catalyst.