Let us consider some class of (Petri) nets. The corresponding Synthesis problem consists in deciding whether a given labeled transition system (TS) A can be implemented by a net N of that class. In case of a negative decision, it may be possible to convert A into an implementable TS B by applying various modification techniques, like relabeling edges that previously had the same label, suppressing edges/states/events, etc. It may however be useful to limit the number of such modifications to stay close to the original problem, or optimize the technique. In this paper, we show that most of the corresponding problems are NP-complete if the considered class corresponds to so-called flip-flop nets or some flip-flop net derivatives.
A novel environmental friendly plasticizer (TPE) derived from tung oil fatty acid with long fatty acid chain and high degree of branching was synthesized. Chemical structure of the obtained TPE was characterized with Fourier transform infrared spectroscopy (FT-IR) and 1H NMR. TPE was used to prepare plasticized PVC blends as main plasticizer. Thermal stability, mechanical properties and migration resistance of poly (vinyl chloride) plasticized with TPE were investigated. The results showed that torque data of plasticized PVC blends reached 12.4 N·m when the mass of the TPE was 50 wt.%. TPE improved the thermal stability of PVC blends obviously than dioctyl phthalate (DOP). The leaching tests showed that PVC plasticized with TPE were with higher migration resistance than that of DOP. The excellent thermal stability and high migration resistance of PVC blends showed high application value for TPE.
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