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Synteza i zastosowanie styrylopochodnych arenów, karbazolu i ferrocenu w projektowaniu e-stereoregularnych krzemoorganicznych materiałów hybrydowych

Majchrzak Mariusz

Wiadomości Chemiczne

2021

[Z] 75, 1-2

137--162

The potential for expanding the variety of catalytic methods for carbon-carbon bond formation is being currently explored in many research centres all over the world. An increasing use of selected d-block metals as catalysts in the synthesis has brought new methods of functionalization of organic and organometallic compounds of great importance for development of polymer chemistry and organic chemical technology [5, 6]. This work describes very precise and controlled catalytic transformations as useful tools for the synthesis of new E-conjugated organic, organosilicon molecular and polymeric compounds. The combination of Suzuki-Miyaura coupling and silylative coupling reactions as a simple and efficient method is established for designing new E-stereoregular hybrid materials in the presence of well-defined transition metal (TM) catalysts. All presented compounds can be interesting precursors for a further functionalization that may significantly increase the possibility of their application in the design and synthesis of new functional materials.

The Facile Synthesis, Theoretical Study and Electrochemical Characterization of Poly(Arylene) Derivatives

Sołoducho J., Doskocz J., Nowakowska A., Cabaj J., Łapkowski M., Golba S.

Polish Journal of Chemistry

2007

Vol. 81, nr 11

2001-2011

A convenient and high yield synthetic route to arylene derivatives was reported and their electrochemical character was shown by properties of polymer with alternate arylene and bispyridine, bisthiophene, bisfurane and bisthiazole units. Polmerization is processed as two steps bielectronic oxidation of molecules. In monoelectronic oxidation stableradical cation is formed with spin located on phenothiazine. The electrochemical properties of polymer are dependent on film thick ness deposited on electrode. In the case of the thin layers one can observe characteristic redox couple of phenothiazine oxidation to radical cation. Analysis of polymer behaviour and results of spectrochemical measurements point on mixed type of electroconducting.