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GC-MS Analysis of n-hexane extracts of Marine Seagrass Posidonia oceanica leaves, rhizomes and roots Collected from Benghazi beach Libya

Elabbar Fakhri, Alasply Abdulsalam

Scientiae Radices

2024

Vol. 3, Iss. 1

1--8

Posidonia oceanica seagrass is endemic to the Mediterranean, and has very little information about volatile organic compounds. The plant was collected from Garyounis Beach in Benghazi, east of Libya, in September 2019. Plant parts, leaves, rhizomes, and roots were extracted using a Soxhlet extractor with Hexane. The compounds were characterized by gas chromatography-mass spectrometry. the extract's chemical constituents were de-convoluted using AMDIS software (www.amdis.net), and the mass spectra of the compounds spectra were explained by fragmentation pattern and matched to authentic standard spectra from Wiley and the NSIT Library database. The results revealed sixteen compounds, dominated by nine long-chain hydrocarbons, three long-chain fatty acids, and a single long-chain ketone. This is the first discovery of 3-ethyl-5-(2ethyl-butyl-octadecane, 6,10,14-trimethylpentadecan-2-one, phytol, and phytyl acetate from this plant.

Combustion performance evaluation of Posidonia oceanica using TGA and bubbling fluidized-bed combustor (batch reactor)

Plis A., Lasek J., Zuwała J., Yu Ch.-Ch., Iluk A.

Journal of Sustainable Mining

2016

Vol. 15, iss. 4

181--190

Combustion performance of emerging raw marine biomass called Posidonia oceanica (PO) was investigated using TGA apparatus and a bubbling fluidized-bed batch reactor. The kinetic mechanism and parameters of the combustion process were determined. The Flynn-Wall-Ozawa (FWO) method and data fitting method were analyzed. It was observed that a model based on consecutive processes: devolatilisation and char combustion for two fractions of PO (holocellulose and lignin), is the best model for the analyzed cases. Combustion performance was observed using a BFB reactor and the composition of flue gas after combustion was analyzed, and the conversion of NOx and SO2 was taken into account. The relatively low SO2 emission in the case of PO combustion can be attributed to the impact of the sulphur self-retention (SSR) process. The results were compared to the combustion of wood biomass and Turow lignite. The results showed the good combustion performance of PO.