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LC-MS/MS monitoring for explosives residues and OGSR with diverse ionization temperatures in soil & hands : 30 minutes for extraction + elution

Şener Harun, Anilanmert Beril, Mavis Murat Emrah, Gursu Gokce Goksu, Cengiz Salih

Acta Chromatographica

2022

Vol. 34, no. 3

304--314

A fast LC-APCI-MS/MS screening/confirmation method was developed and validated for trace analyses of 18 analytes which are explosives and organic gun shot residues including the challenging ones with diverse ionization conditions, in soil and on hands. (+) and (−) ionization modes were used after a single-step, low-volume solvent extraction procedure developed using methanol. Tape-lifting, stub, alcohol wipes, cotton bud were compared for collecting the residues from hands of a shooter. Tape-lifting and stub gave the highest recoveries and tape-lifting was chosen. Gradient elution system using ammonium chloride:methanol was developed. Whole procedure lasted approximately 30 min, was validated in both matrices, applied to real samples as post-blast residues, smokeless powder and the hands of a shooter, after shooting. Most of the recoveries were >80% and since all the precisions were <15%, quantitation was possible for all. Limit of Detection (LOD) and Limit of Quantification (LOQ) values were: 0.2–54.1 and 0.3–190.0 ngg⁻¹ in soil, and 0.2–132.3 and 1.1–355.0 ngg⁻¹ in tape-lift.

Preparation of Heat Resistant and Insensitive Explosives by Vicarious Nucleophilic Substitution (VNS) in Polinitroaromatic Compounds

Szala M., Jończyk A., Skupiński W.

Central European Journal of Energetic Materials

2005

Vol. 2, nr 2

15-27

Reaction of vicarious nucleophilic substitution (VNS) of hydrogen was applied for preparation of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB) in a twostep process. Using this approach 3-amino-2,4,6'2'4 6' -hexanitrostilbene (MNHNS) and new 2,6-bis(3-amino-2,4,6-trinitrophenyl)-3,5-dinitropyridine (DAPYX) were obtained.