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Cation of N-Allylbenzothiazolium as a P-Ligand in Copper(I) Halide Complexes: Synthesis and Crystal Structure of [C7H5NS(C3H5)]+.CuCIcl2.H2O and [C7H5NS(C3H5)]+.CuCl1.06Br0.94.H2O Compunds

Goreshnik E., Mys'kiv M.

Polish Journal of Chemistry

1999

Vol. 73, nr 8

1245-1252

By alternating-current electrochemical synthesis crystals of [ ] P-complexes have been obtained and structurally characterized. Owing to the cationic form, the ligand is coordinated to Cu atom only through the C=C bond. Due to the bridge role of X(2) atom [X=Cl(I) or statistic mixture Cl, Br (II))}, cyclic fragments Cu2X2 appear.