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Computer Simulation of Microsegregation of Sulphur and Manganese and Formation of MnS Inclusions while Casting Rail Steel

Kalisz D., Gerasin S., Bobrowski P., Żak P. L., Skowronek T.

Archives of Metallurgy and Materials

2016

Vol. 61, iss. 4

1939--1944

The quality of rail steel is conditioned by its high mechanic qualities, which greatly depend on the presence of undesired nonmetallic inclusions. The paper is devoted to the segregation of components, mainly sulphur, and the formation of manganese sulphide in the process of steel solidification, at the casting rate of 100 and 500 K/min. Sulphur is a steel component which disadvantageously influences its numerous parameters. The oxide-sulphide and sulphide precipitations cause cracks and lower the strength of the material. This phenomenon was modeled with the use of author’s computer program based on Matsumiya interdendritic microsegregation model. The main assumptions of this model and thermodynamic conditions of inclusion formation during casting of steel are discussed in this paper. Two cases were analyzed: in the first one the MnS was assumed to form a pure and constant compound, whereas in the other one the manganese sulfide was precipitated as a component of a liquid oxide solution, and its activity was lower than unity. The final conclusion is that chemical composition of steel is the major parameter deciding about the formation of MnS inclusions.

Modeling of the Mn and S Microsegregation During Continuous Casting of Rail Steel

Gerasin S., Kalisz D.

Archives of Foundry Engineering

2015

Vol. 15, iss. 4 spec.

35--38

The aim of this study was to analyze the process of manganese sulfide formation based on thermodynamics calculation. Both experimental and theoretical analysis methods were used in this work. Computer simulation with the use of non-commercial software was used for the calculation of the process of segregation of manganese and sulfur and MnS non-metallic particles precipitates in liquid steel during solidification of ingot. The curves illustrating the inclusion formation process are presented. MnS inclusions are disposed along grain boundaries in thin layers and have a rounded shape.

W pracy analizowano proces powstawania siarczku manganu w oparciu o obliczenia termodynamiczne. Wyniki przedstawiono w odniesieniu do badań eksperymentalnych. Symulacje komputerowe procesu segregacji manganu i siarki oraz powstawania wydzieleń MnS podczas krzepnięcia stali zostały wykonane za pomocą nie komercyjnego programu komputerowego. Rezultaty symulacji komputerowej przedstawiono w postaci wykresów prezentujących segregację składników oraz krzywych obrazujących proces powstawania wydzieleń. Wtrącenia MnS są rozmieszczone wzdłuż granic ziaren i mają zaokrąglony kształt.