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Quorum Sensing Materials as New Ligand for Palladium Catalyzed Migita-Kosugi-Stille Polycondensation

Wang A., Toyofuku M., Nomura N., Goto H.

International Letters of Chemistry, Physics and Astronomy

2014

Vol. 13, iss. 1

62-70

Signal molecules for quorum sensing are employed for ligands to palladium. The complex can be used as a catalyst. Migita-Kosugi-Stille coupling reactions are driven by using a series of N-(3- oxo-acyl)-L-homoserine lactones as ligands coordinating with Pd. Catalysis of [Pd-(signal molecules for quorum sensing), or Pd/QS] allows production of conjugated polymers with light-emitting functions.