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The using possibility of clay-rich overburden rocks from selected Polish deposits

Bożęcki P., Rzepa G.

Geology, Geophysics and Environment

2012

Vol. 38, no. 4

457

The objective of this work was an assessment of the possibility of utilization of selected clay-rich overburden rocks from selected rock raw material found in Polish deposits. For this purpose samples from 12 deposits in five different provinces of southern Poland (Małopolskie, Śląskie, Podkarpackie, Dolnośląskie and Świętokrzyskie) have been collected. Exploited mineral deposits from which samples have been taken belong to wide range of materials. They are for example dolomite (Rędziny), magnesite (Braszowice), limestone (Czatkowice and Morawica), rhyodacites (Zalas), clay materials for construction of ceramics (Harasiuki, Wala Rzedzińska, Kraniec, Wręczyca) and mineral aggregates like sand (Bielany at Sole and Wola Batorska). Main field of feasibility of using samples were components of waterproofing layers. Part of the samples was also tested for the possibility of their use in land reclamation. Mineral and chemical composition of the samples was analysed, using XRD and ICP-OAS methods, respectively. Grain size distribution was performed by using sieve analysis and by a laser particle size analyser. Exchangeable cations and cation exchange capacity were also estimated based on the concentration of displaced ions (such as Ba +, Fe +, Sr +, Al +, Mg +, Ca +, Na+, K+, Li+) by ammonium cation (from the 1 M ammonium acetate solution) and indicated cations. Results of this study show that none of the tested samples met all the requirements for components of hydro-isolation layer, and therefore they cannot be used for this purpose. In most cases this is an effect of unfavourable mineral composition (to high percentage of non-clay minerals) and/or chemical composition. Usually the amount of examined exchangeable cations was also incorrect. The applicability results for land reclamation showed a very large variation. Part of the samples has acquired the highest A class. However, some samples were also found to be characterized by the worst D class of reclamation utility.