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An Evaluation of Combustion Kinetics for the Synthesis Reaction of the Reinforcing Phase During Casting

Wiktor Tomasz, Sobula Sebastian, Burbelko Andriy, Ptasznik Michał

Journal of Casting & Materials Engineering

2020

Vol. 4, no. 2

23--28

The computer modeling of the solidification process in castings with local composite reinforcement (LCR) obtained as a result of in situ reactions of self-propagating high temperature synthesis (SHS) is difficult due to limited data on the thermo-physical parameters of exothermic effects and the kinetics of the synthesis reaction. In the present study, Hadfield cast steel casting was manufactured with LCR containing titanium carbide particles obtained in situ by the SHS method. Reaction kinetics of titanium carbide synthesis in the composite casting were determined on the basis of temperature measurements in the area of LCR during the process. For the estimation of the reaction, the Fourier Thermal Analysis method was used. The paper presents the results of temperature measurement and the results of the calculation of SHS reaction kinetics. It was found that the reaction time under the conditions of the analyzed casting is below 3 s.

New Possibilities in Thermal Analysis of Molding Materials

Svidró J., Diószegi A.

Journal of Casting & Materials Engineering

2018

Vol. 2, no. 4

67--70

Molding material-related studies within the research activities concerning foundry technology have always been limited despite the significant effect of molding mixtures on the quality of cast parts. One reason behind this trend is the difficulty in interpreting the results of such complex systems like molds and cores. This paper provides a new possibility for studying the heat-absorption performance of materials used as molding media in metal casting processes. By further developing the Fourier thermal analysis method of cores and molds introduced by earlier studies, the investigation of unbonded sand has become available. The heat-absorption properties of the components can be hereby separated and studied respectively. Thermal analyses were performed on sphere-shaped resin-bonded cores with various binder levels as well as on unbonded sand samples. The temperature data collected from two points of the samples were then used for the calculation of the novel thermophysical properties. The results revealed not only quantitative but qualitative differences in the characteristics of the binder decomposition processes, providing a deeper understanding on the thermal behavior of molding materials. The outcome of the research provides more accurate data, which is the key for the improved simulation of casting processes.