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1
Content available Thermodynamic Description of Ternary Fe-B-X Systems. Part 9: Fe-B-Cu
Miettinen Jyrki, Visuri Ville-Valtteri, Fabritius Timo
Archives of Metallurgy and Materials
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2021
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Vol. 66, iss. 1
297--304
EN
Thermodynamic descriptions of the ternary Fe-B-Cu system and its binary sub-system B-Cu aredeveloped in the context of a new Fe-B-X (X = Cr, Cu, Mn, Mo, Ni, Si, Ti, V, C) database. The thermodynamic parameters of the other binary sub-systems (Fe-B and Fe-Cu) are taken from earlier assessments. Experimental thermodynamic and phase equilibrium data available in the literature have been used for the optimization of the Fe-B-Cu and B-Cu systems’ thermodynamic parameters. The solution phases are described using a substitutional solution model and the compounds (two borides of the Fe-B system) are treated as stoichiometric phases. A good agreement was obtained between the calculated and the experimental thermodynamic and phase equilibrium data.
2
Content available Thermodynamic Description of Ternary Fe-B-X Systems. Part 8: Fe-B-Mo, with Extension to Quaternary Fe-B-Cr-Mo System
Miettinen Jyrki, Visuri Ville-Valtteri, Fabritius Timo
Archives of Metallurgy and Materials
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2021
|
Vol. 66, iss. 1
281--295
EN
Thermodynamic optimizations of the ternary Fe-B-Mo system and its binary sub-system B-Mo are presented. The Fe-B-Mo description is then extended to the quaternary Fe-B-Cr-Mo system by assessing the ternary B-Cr-Mo system. The thermodynamic descriptions of the other binaries (Fe-B, Fe-Cr, Fe-Mo, B-Cr, and Cr-Mo) and the other ternaries (Fe-B-Cr and Fe-Cr-Mo) are taken from earlier studies. In this study, the adjustable parameters of the B-Mo, Fe-B-Mo, and B-Cr-Mo systems were optimized using the experimental thermodynamic and the phase equilibrium data from the literature. The solution phases of the system (liquid, bcc and fcc) are described with the substitutional solution model, and most borides are treated as stoichiometric phases or semistoichiometric phases, using a simple two-sublattice model for the latter. The system’s intermetallic phases, Chi, Mu, R, and Sigma (not dissolving boron) as well as boride M3B2, based on a formulation of (Cr,Fe)(Cr,Fe,Mo)2(B)2, are described with a three-sublattice model. Reasonable agreement is obtained between the calculated and measured phase equilibria in all four systems: B-Mo; Fe-B-Mo; B-Cr-Mo; and Fe-B-Cr-Mo.
3
Content available Thermodynamic Description of Ternary Fe-B-X Systems. Part 6: Fe-B-Ti
Miettinen J., Visuri V.-V., Fabritius T., Milcheva N., Vassilev G.
Archives of Metallurgy and Materials
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2019
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Vol. 64, iss. 4
1249--1255
EN
Thermodynamic optimizations of the ternary Fe-B-Ti system and its binary sub-system, B-Ti are presented. The thermodynamic descriptions of the other binaries, Fe-Ti and Fe-B, are taken from the earlier studies slightly modifying the Fe-Ti system assessment. The adjustable parameters of the Fe-B-Ti and B-Ti systems are optimized in this study using the experimental thermodynamic and the phase equilibrium data from the literature. The solution phases of the system are described using the substitutional solution model and the compounds (including borides) are treated as stoichiometric phases. The results show a good correlation between the calculated and measured thermodynamic and phase equilibrium data.
4
Content available Thermodynamic Description of Ternary Fe-B-X Systems. Part 5: Fe-B-Si
Miettinen J., Visuri V.-V., Fabritius T., Milcheva N., Vassilev G.
Archives of Metallurgy and Materials
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2019
|
Vol. 64, iss. 4
1239--1248
EN
Thermodynamic descriptions of the ternary Fe-B-Si system and its binary sub-system, B-Si, are developed in the context of a new Fe-B-X (X = Cr, Ni, Mn, V, Si, Ti, C) database. The thermodynamic parameters of the other binary sub-systems, Fe-Si and Fe-B, are taken from earlier assessments. Experimental thermodynamic and phase equilibrium data available in the literature has been used for the optimization of the thermodynamic parameters of the Fe-B-Si and B-Si systems. The solution phases are described using substitutional solution model and the compounds (silicides and borides) are treated as stoichiometric phases. The calculated and experimental thermodynamic and phase equilibrium data were found to be in good agreement.
5
Content available Thermodynamic Description of Ternary Fe-B-X Systems. Part 4: Fe-B-V
Miettinen J., Visuri V.-V., Fabritius T., Milcheva N., Vassilev G.
Archives of Metallurgy and Materials
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2019
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Vol. 64, iss. 2
451--456
EN
Thermodynamic descriptions of the ternary Fe-B-V system and its binary sub-system B-V, are developed using experimental thermodynamic and phase equilibrium data from the literature. The thermodynamic parameters of the other binaries, Fe-V and Fe-B, are taken from earlier assessments slightly modifying the Fe-V description. The work is in the context of a new Fe-B-X (X = Cr, Ni, Mn, V, Si, Ti, C) database. The solution phases are described using substitutional solution model. The borides are treated as stoichiometric or semistoichiometric phases and described with two-sublattice models.
6
Content available Thermodynamic Description of Ternary Fe-B-X Systems. Part 3: Fe-B-Mn
Miettinen J., Lilova K., Vassilev G.
Archives of Metallurgy and Materials
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2014
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Vol. 59, iss. 4
1481--1485
EN
A thermodynamic optimization of the ternary Fe-B-Mn system is presented. The thermodynamic parameters of the binary sub-systems, Fe-Mn, Fe-B and B-Mn, are taken from earlier assessments slightly modifying the B-Mn system description. The thermodynamic parameters of the Fe-B-Mn system are optimized in this study using literature experimental thermodynamic and phase equilibrium data. The solution phases of the system are described using the substitutional solution model and the borides are treated as stoichiometric or semi-stoichiometric phases of the (A,B)pCq type described with the two-sublattice models.
PL
Przedstawiono termodynamiczny opis trójskładnikowego układu Fe-B-Mn. Parametry termodynamiczne dwuskładnikowych stopów Fe-Mn, Fe-B i B-Mn zostały zaczerpnięte z wcześniejszych opracowań, przy tym opis układu B-Mn został nieznacznie zmodyfikowany. Parametry termodynamiczne dla układu Fe-B-Mn zostały zoptymalizowane w tej pracy w oparciu o eksperymentalne równowagi fazowe i dane termodynamiczne zaczerpnięte z literatury. Roztwory stałe w układzie Fe-B-Mn opisano przy użyciu modelu roztworu substytucyjnego, a borki traktowane sa jako fazy stechiometryczne lub półstechiometryczne typu (A,B)pCq opisane przy użyciu modelu dwu podsieci.
7
Content available Thermodynamic Description Of Ternary Fe-B-X Systems. Part 2: Fe-B-Ni
Miettinen J., Vassilev G.
Archives of Metallurgy and Materials
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2014
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Vol. 59, iss. 2
609--614
PL
Opis termodynamiczny trójskładnikowych układów Fe-B-X. Część 2: Fe-B-Ni
8
Content available Thermodynamic Description of Ternary Fe-B-X Systems. Part 1: Fe-B-Cr
Miettinen J., Vassilev G.
Archives of Metallurgy and Materials
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2014
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Vol. 59, iss. 2
601--607
EN
A thermodynamic description of the Fe-B-Cr system is developed in the context of a new Fe-B-X (X = Cr, Ni, Mn, Si, Ti, V, C) database. The thermodynamic parameters of the binary sub-systems, Fe-B, Fe-Cr and B-Cr, are taken from earlier assessments slightly modifying the Fe-B and B-Cr descriptions, and those of the ternary system are optimized in this study using experimental thermodynamic and phase equilibrium data from the literature. The solution phases are described using substitutional solution model. The borides are treated as stoichiometric or semi-stoichiometric phases and described with two-sublattice models.
PL
Przedstawiono termodynamiczny opis trójskładnikowego układu Fe-B-Cr w kontekście bazy danych dla układów Fe-B-X (X = Cr, Ni, Mn, Si, Ti, V, C). Parametry termodynamiczne dwuskładnikowych stopów Fe-Mn, Fe-B i Mn-B zostały są zaczerpnięte z wcześniejszych opracowań, przy tym opisy Fe-B i B-Cr zostały nieznacznie zmodyfikowane. Parametry dla układu Fe-Mn-B zostały zoptymalizowane w tej pracy w oparciu o eksperymentalne równowagi fazowe i dane termodynamiczne zaczerpnięte z literatury. Roztwory stałe opisano przy użyciu modelu roztworu substytucyjnego, a borki traktowane są jako fazy stechiometryczne lub półstechiometryczne opisane przy użyciu modelu dwu podsieci.
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