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Multi-variant Sorption Optimization for the Uptake Of Pb(II) Ions by Jamun Seed Waste

Siyal A.N., Memon S.Q., Amanullah M., Pirzada T., Parveen S. S.

Polish Journal of Chemical Technology

2013

Vol. 15, nr 1

15-21

In the present study, jamun seed waste has been explored for the removal of Pb(II) ions from aqueous solution. The multi-variant sorption optimization was achieved by the factorial design approach. 99.91% of Pb(II) ions was removed from aqueous solution. The results predicted by the model were in good agreement with the experimental results (the values of R2 and R2 adj. were found to be 99.89% and 99.95%, respectively). Langmuir and D-R isotherm studies were carried out to fi nd adsorbent's capacities (183.9 š 0.31 mg/g and 184.5 š 0.16 mg/g respectively), sorption free energy 13.17 š 0.16 and RL values in the range of 0.05-0.77, suggested the favorable chemical and/or ion exchange nature of the sorption process. The FT-IR study was carried out for unloaded and Pb(II) ions loaded jamun seed, indicated, Pb(II) ions associated with nitrogen and oxygen of jamun seed containing moieties during the adsorption process. The proposed method was successfully validated and applied for the treatment of Pb(II) ions contaminating drinking water.

Recycling of styrofoam waste: synthesis, characterization and application of novel phenyl thiosemicarbazone surface

Siyal A.N., Memon S.Q., Khuhawar M.Y.

Polish Journal of Chemical Technology

2012

Vol. 14, nr 4

11-18

An attempt has been made to recycle Styrofoam waste to a novel functional polymer, Phenyl thiosemicarbazone surface (PTS). Polystyrene (PS) obtained from Styrofoam waste was acetylated and then condensed to PTS by reacting it with 4-Phenyl-3-thiosemicarbazide ligand and characterized by FT-IR spectroscopy and elemental analysis. Synthesized PTS was applied successfully for the treatment of lead contaminated water by batch extraction method. Sorption variables were optimized (pH 8, adsorbent dose 53mg, initial Pb(II) ion concentration 10mgl-1 and agitation time 90min) by factorial design approach. Lead uptake by PTS was found much sensitive to the pH of Pb(II) ion solution. The maximum removal (99.61%) of Pb(II) ions was achieved at optimum conditions. The Langmuir and D-R isotherm study suggested the monolayer, favorable (RL=0.0001-0.01) and chemisorption (E=20.41š0.12kJmol-1) nature of the adsorption process. The sorption capacity of PTS was found to be 45.25š0.69mgg-1. The FT-IR spectroscopy study showed the involvement of nitrogen and sulphur of thiosemicarbazone moiety of PTS for the uptake of Pb(II) ions by fi ve membered chelate formation.