The paper is a detailed analysis of the devices used in measurements of hydrocarbon content on gas carriers during cargo tank gassing-up operations. The characteristics of the Riken Keiki GX-8000 portable gas detector used commonly on ships are described, the types of detection used in the device in relation to the detected gases are discussed, which made it possible to question the validity of using the detector for analysing the concentrations of large quantities of hydrocarbons on gas carriers. Also discussed is a device enabling such analyses to be carried out much more accurately – the Agilent 490 Micro GC chromatograph, which will substantially improve the process of cargo tank gassing-up.
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Ethylene is one of the basic raw materials of the petrochemical industry used for the production of plastics, mainly plastic packaging. The USA is the largest producer of this compound. The enormous increase in demand for Ethylene has been observed in recent years in China as well as in the Middle and Far East. This caused an unprecedented increase in the demand for transport of this cargo by sea. Ethylene carriers for its transport are special construction LPG vessels, having a cascade cycle with Propylene medium (less often the refrigerant R 404 A). They have been designed in such a way as to withstand a working pressure of up to 5.4 bar, and the minimum temperature of the transported load is minus 104⁰C for fully cooled Ethylene. This cargo is explosive in the mixture with air (within concentrations of 2.75-2.6%) and during heating under elevation pressure. Therefore, it is required to transport Ethylene in with an inert gas, most often Nitrogen. During the operation of LPG carriers carrying Ethylene, processes of aeration, inerting, gassing-up, cooling tanks and a cargo are repeatedly carried out. The most problematic to carry is gassing-up operation, because it is associated with significant amounts of Ethylene loss, this causes large financial losses. In the article, the authors attempted to diagnose the most serious problems during carrying out the most important for cargo loss the cargo handling operations.
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